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Question 60

The difference in the oxidation state of Xe between the oxidised product of Xe formed on complete hydrolysis of XeF$$_4$$ and XeF$$_4$$ is _______


Correct Answer: 2

We need to find the difference in oxidation state of Xe between the oxidized product formed on complete hydrolysis of $$XeF_4$$ and $$XeF_4$$ itself.

The complete hydrolysis of $$XeF_4$$ is a disproportionation reaction:

$$6XeF_4 + 12H_2O \rightarrow 4Xe + 2XeO_3 + 24HF + 3O_2$$

In this reaction, $$XeF_4$$ undergoes disproportionation - some Xe is reduced to elemental form (Xe) and some is oxidized to $$XeO_3$$.

In $$XeF_4$$: F has oxidation state $$-1$$. So $$x + 4(-1) = 0$$, giving $$x = +4$$.

In $$XeO_3$$ (oxidized product): O has oxidation state $$-2$$. So $$x + 3(-2) = 0$$, giving $$x = +6$$.

In Xe (reduced product): Oxidation state = 0.

The oxidized product is $$XeO_3$$ (Xe in +6 state). The oxidation state of Xe in $$XeF_4$$ is +4.

$$\text{Difference} = (+6) - (+4) = 2$$

The difference in the oxidation state is 2.

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