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The denticity of the ligand present in the Fehling's reagent is ______.
Correct Answer: 2
Find the denticity of the ligand present in Fehling's reagent.
Identify the components of Fehling's reagent.
Fehling's reagent is a mixture of:
Fehling's solution A: Aqueous CuSO$$_4$$
Fehling's solution B: Alkaline sodium potassium tartrate (Rochelle salt, NaKC$$_4$$H$$_4$$O$$_6$$)
The ligand in Fehling's reagent is the tartrate ion ($$\text{C}_4\text{H}_4\text{O}_6^{2-}$$), which is 2,3-dihydroxybutanedioate.
Determine the denticity.
The tartrate ion coordinates to Cu$$^{2+}$$ through its donor atoms. In Fehling's reagent, tartrate acts as a bidentate ligand, coordinating through two oxygen atoms (one from a hydroxyl group and one from a carboxylate group).
Denticity = 2.
The correct answer is 2.
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