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Question 59

The oxidation state of manganese in the product obtained in a reaction of potassium permanganate and hydrogen peroxide in basic medium is


Correct Answer: 4

We need to find the oxidation state of manganese in the product formed when potassium permanganate reacts with hydrogen peroxide in basic medium.

In basic medium, $$KMnO_4$$ reacts with $$H_2O_2$$ as follows: $$2KMnO_4 + 3H_2O_2 \rightarrow 2MnO_2 + 2KOH + 3O_2 + 2H_2O$$.

Since the permanganate ion is reduced in this reaction, the manganese-containing product is manganese dioxide, $$MnO_2$$, which appears as a brown precipitate.

Let the oxidation state of Mn in $$MnO_2$$ be $$x$$. Substituting into the charge balance gives $$x + 2(-2) = 0$$.

From the above equation, we have $$x - 4 = 0$$, which leads to $$x = +4$$.

Therefore, the oxidation state of manganese changes from +7 in $$KMnO_4$$ to +4 in $$MnO_2$$.

Hence, the answer is 4.

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