Join WhatsApp Icon JEE WhatsApp Group
Question 55

A solution containing $$10 \text{ g}$$ of an electrolyte $$AB_2$$ in $$100 \text{ g}$$ of water boils at $$100.52°C$$. The degree of ionization of the electrolyte $$(\alpha)$$ is ______ $$\times 10^{-1}$$. (nearest integer) [Given: Molar mass of $$AB_2 = 200 \text{ g mol}^{-1}$$, $$K_b$$ (molal boiling point elevation const. of water) $$= 0.52 \text{ K kg mol}^{-1}$$, boiling point of water $$= 100°C$$; $$AB_2$$ ionises as $$AB_2 \rightarrow A^{2+} + 2B^-$$]


Correct Answer: 5

Find the degree of ionization $$\alpha$$ for electrolyte $$AB_2$$.

Boiling point elevation is calculated as $$\Delta T_b = 100.52 - 100 = 0.52°C$$.

Since $$\Delta T_b = iK_bm$$, where $$m$$ is the molality, we first determine $$m$$.

Substituting the values gives $$m = \frac{10/200}{100/1000} = \frac{0.05}{0.1} = 0.5 \text{ mol/kg}$$.

Using $$\Delta T_b = iK_bm$$ again with $$0.52 = i \times 0.52 \times 0.5$$ leads to $$i = \frac{0.52}{0.26} = 2$$.

The dissociation of $$AB_2$$ is represented by $$AB_2 \rightarrow A^{2+} + 2B^-$$, yielding $$n = 3$$ ions.

Relating the van't Hoff factor to the degree of ionization via $$i = 1 + (n-1)\alpha$$, we have $$2 = 1 + 2\alpha$$, which gives $$\alpha = 0.5$$.

Therefore, $$\alpha = 0.5 = 5 \times 10^{-1}$$.

The correct answer is 5.

Get AI Help

Video Solution

video

Create a FREE account and get:

  • Free JEE Mains Previous Papers PDF
  • Take JEE Mains paper tests

JEE Quant Questions | JEE Quantitative Ability

JEE DILR Questions | LRDI Questions For JEE

JEE Verbal Ability Questions | VARC Questions For JEE

Free JEE Topicwise Questions

JEE Rotational MotionJEE Units & MeasurementsJEE Atomic StructureJEE GravitationJEE Periodic Table & PeriodicityJEE StatisticsJEE Inverse Trigonometric FunctionsJEE Magnetism & Magnetic MaterialsJEE Sequences & SeriesJEE MatricesJEE Alternating CurrentsJEE Carboxylic AcidsJEE Permutations & CombinationsJEE Work, Energy & PowerJEE Electromagnetic InductionJEE Electronic DevicesJEE d and f-Block ElementsJEE Chemical KineticsJEE Heat TransferJEE Three Dimensional GeometryJEE Magnetic Effects of CurrentJEE Hydrocarbons - AromaticJEE Electromagnetic WavesJEE Aldehydes & KetonesJEE Hydrocarbons - AlkanesJEE Applications of DerivativesJEE EquilibriumJEE Indefinite IntegrationJEE Chemical ThermodynamicsJEE ElectrochemistryJEE ProbabilityJEE BiomoleculesJEE Continuity & DifferentiabilityJEE Kinetic Theory of GasesJEE Vector AlgebraJEE Hydrocarbons - AlkynesJEE Differential EquationsJEE Current & ResistanceJEE Straight LinesJEE WavesJEE Redox ReactionsJEE Hydrocarbons - AlkenesJEE DeterminantsJEE SolutionsJEE Ray OpticsJEE Dual Nature of Matter & RadiationJEE Chemical Bonding & Molecular StructureJEE Complex NumbersJEE Sets, Relations & FunctionsJEE Electric Charges & FieldsJEE Laws of MotionJEE Fluid MechanicsJEE Basic Concepts in ChemistryJEE Trigonometric FunctionsJEE LimitsJEE Laws of ThermodynamicsJEE Kinematics - 2D MotionJEE p-Block Elements (Groups 13-18)JEE Simple Harmonic MotionJEE Electric Potential & CapacitanceJEE Coordination CompoundsJEE JEE 2D GeometryJEE CirclesJEE Definite IntegrationJEE EMF & Circuit AnalysisJEE Surface TensionJEE Atoms & NucleiJEE Laboratory Experiments - XIJEE Number SystemJEE Basic Principles of Organic ChemistryJEE Wave OpticsJEE Quadratic EquationsJEE Alcohols, Phenols & EthersJEE Organic Compounds with HalogensJEE DifferentiationJEE Conic SectionsJEE Nitrogen-Containing CompoundsJEE ElasticityJEE Practical Organic ChemistryJEE Kinematics - 1D MotionJEE Purification & CharacterisationJEE Binomial Theorem
Ask AI