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Question 48

In a conductometric titration, small volume of titrant of higher concentration is added stepwise to a larger volume of titrate of much lower concentration, and the conductance is measured after each addition.

The limiting ionic conductivity ($$\Lambda_0$$) values (in mS $$m^2$$ $$mol^{-1}$$) for different ions in aqueous solutions are given below:

Ions$$Ag^+$$$$K^+$$$$Na^+$$$$H^+$$$$NO_3^-$$$$Cl^-$$$$SO_4^{2-}$$$$OH^-$$$$CH_3COO^-$$
$$\Lambda_0$$6.27.45.035.07.27.616.019.94.1

For different combinations of titrates and titrants given in List-I, the graphs of 'conductance' versus 'volume of titrant' are given in List-II.

Match each entry in List-I with the appropriate entry in List-II and choose the correct option.

List-IList-II
(P)Titrate: KCl
Titrant: $$AgNO_3$$
(1)
image
(Q)Titrate: $$AgNO_3$$
Titrant: KCl
(2)
image
(R)Titrate: NaOH
Titrant: HCl
(3)
image
(S)Titrate: NaOH
Titrant: $$CH_3COOH$$
(4)
image
(5)
image

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