Join WhatsApp Icon JEE WhatsApp Group
Question 47

When ethanol is heated with conc. $$H_2SO_4$$, a gas is produced. The compound formed, when this gas is treated with cold dilute aqueous solution of Baeyer's reagent, is

When ethanol is heated with concentrated sulfuric acid, it undergoes dehydration. Dehydration is a reaction where a molecule loses water. The reaction for ethanol with concentrated sulfuric acid is:

First, ethanol has the formula CH₃CH₂OH. Concentrated sulfuric acid acts as a dehydrating agent and removes a water molecule. The reaction is:

$$ CH_{3}CH_{2}OH ->[conc. H_{2}SO_{4}][heat] CH_{2}=CH_{2} + H_{2}O $$

So, ethanol (CH₃CH₂OH) loses a water molecule (H₂O) to form ethene gas (CH₂=CH₂). Therefore, the gas produced is ethene.

Now, this gas (ethene) is treated with cold dilute aqueous solution of Baeyer's reagent. Baeyer's reagent is an alkaline solution of potassium permanganate (KMnO₄). It is used to test for unsaturation in organic compounds. When an alkene like ethene is treated with cold dilute Baeyer's reagent, it undergoes hydroxylation. Hydroxylation adds hydroxyl groups (-OH) across the double bond.

The reaction for ethene with Baeyer's reagent is:

$$ CH_{2}=CH_{2} + [O] + H_{2}O ->[cold, dil. KMnO_{4}] HO-CH_{2}-CH_{2}-OH $$

Here, [O] represents the oxidizing agent (from KMnO₄). The product is ethane-1,2-diol, commonly known as ethylene glycol or simply glycol. Its formula is HO-CH₂-CH₂-OH.

Therefore, the compound formed is glycol.

Now, looking at the options:

A. Formaldehyde (HCHO)

B. Formic acid (HCOOH)

C. Glycol (HOCH₂CH₂OH)

D. Ethanoic acid (CH₃COOH)

Option C matches the compound formed, which is glycol.

Hence, the correct answer is Option C.

Get AI Help

Video Solution

video

Create a FREE account and get:

  • Free JEE Mains Previous Papers PDF
  • Take JEE Mains paper tests

JEE Quant Questions | JEE Quantitative Ability

JEE DILR Questions | LRDI Questions For JEE

JEE Verbal Ability Questions | VARC Questions For JEE

Free JEE Topicwise Questions

JEE Rotational MotionJEE Units & MeasurementsJEE Atomic StructureJEE GravitationJEE Periodic Table & PeriodicityJEE StatisticsJEE Inverse Trigonometric FunctionsJEE Magnetism & Magnetic MaterialsJEE Sequences & SeriesJEE MatricesJEE Alternating CurrentsJEE Carboxylic AcidsJEE Permutations & CombinationsJEE Work, Energy & PowerJEE Electromagnetic InductionJEE Electronic DevicesJEE d and f-Block ElementsJEE Chemical KineticsJEE Heat TransferJEE Three Dimensional GeometryJEE Magnetic Effects of CurrentJEE Hydrocarbons - AromaticJEE Electromagnetic WavesJEE Aldehydes & KetonesJEE Hydrocarbons - AlkanesJEE Applications of DerivativesJEE EquilibriumJEE Indefinite IntegrationJEE Chemical ThermodynamicsJEE ElectrochemistryJEE ProbabilityJEE BiomoleculesJEE Continuity & DifferentiabilityJEE Kinetic Theory of GasesJEE Vector AlgebraJEE Hydrocarbons - AlkynesJEE Differential EquationsJEE Current & ResistanceJEE Straight LinesJEE WavesJEE Redox ReactionsJEE Hydrocarbons - AlkenesJEE DeterminantsJEE SolutionsJEE Ray OpticsJEE Dual Nature of Matter & RadiationJEE Chemical Bonding & Molecular StructureJEE Complex NumbersJEE Sets, Relations & FunctionsJEE Electric Charges & FieldsJEE Laws of MotionJEE Fluid MechanicsJEE Basic Concepts in ChemistryJEE Trigonometric FunctionsJEE LimitsJEE Laws of ThermodynamicsJEE Kinematics - 2D MotionJEE p-Block Elements (Groups 13-18)JEE Simple Harmonic MotionJEE Electric Potential & CapacitanceJEE Coordination CompoundsJEE JEE 2D GeometryJEE CirclesJEE Definite IntegrationJEE EMF & Circuit AnalysisJEE Surface TensionJEE Atoms & NucleiJEE Laboratory Experiments - XIJEE Number SystemJEE Basic Principles of Organic ChemistryJEE Wave OpticsJEE Quadratic EquationsJEE Alcohols, Phenols & EthersJEE Organic Compounds with HalogensJEE DifferentiationJEE Conic SectionsJEE Nitrogen-Containing CompoundsJEE ElasticityJEE Practical Organic ChemistryJEE Kinematics - 1D MotionJEE Purification & CharacterisationJEE Binomial Theorem
Ask AI