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Question 46

Considering the above chemical reaction, identify the product X:

Solution

The given reaction is carried out in basic medium and followed by heating. Such a sequence is typical for an aldol condensation.

Step 1 (Enolate formation)
Under the action of a dilute base, the carbonyl compound loses an $$\alpha$$-hydrogen to give an enolate ion.
For ethanal (acetaldehyde):
$$CH_3CHO + OH^- \;\rightarrow\; CH_2^-CHO + H_2O$$

Step 2 (Nucleophilic addition)
The enolate ion now attacks the carbonyl carbon of a second, unchanged ethanal molecule to form the β-hydroxy aldehyde (the aldol).
$$CH_2^-CHO + CH_3CHO \;\rightarrow\; CH_3CH(OH)CH_2CHO$$

Step 3 (Dehydration on heating)
When the reaction mixture is warmed, the β-hydroxy aldehyde loses a molecule of water to give an $$\alpha,\beta$$-unsaturated aldehyde.
$$CH_3CH(OH)CH_2CHO \;\xrightarrow{\ \Delta\ }\; CH_3CH=CHCHO + H_2O$$

The product obtained is crotonaldehyde, $$CH_3CH=CHCHO$$, an $$\alpha,\beta$$-unsaturated aldehyde.

Among the given choices, Option C (Option 3) represents crotonaldehyde. Hence, the correct product X is Option C.

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