Join WhatsApp Icon JEE WhatsApp Group
Question 44

Which of the following statements are correct?
(A) The M$$^{3+}$$/M$$^{2+}$$ reduction potential for iron is greater than manganese.
(B) The higher oxidation states of first row d-block elements get stabilized by oxide ion
(C) Aqueous solution of Cr$$^{2+}$$ can liberate hydrogen from dilute acid
(D) Magnetic moment of V$$^{2+}$$ is observed between 4.4-5.2 BM
Choose the correct answer from the options given below:

Let us analyze each statement:

(A) M³⁺/M²⁺ reduction potential: Fe³⁺/Fe²⁺ = +0.77 V, Mn³⁺/Mn²⁺ = +1.51 V. Actually Mn³⁺/Mn²⁺ is higher. So this statement is incorrect.

(B) Higher oxidation states of first row d-block elements are stabilized by oxide ion (due to its small size and ability to form multiple bonds). This is correct. Example: CrO₄²⁻, MnO₄⁻.

(C) Cr²⁺ is a strong reducing agent (E° for Cr³⁺/Cr²⁺ = -0.41 V), so it can reduce H⁺ to H₂. Cr²⁺(aq) can liberate hydrogen from dilute acid. This is correct.

(D) V²⁺ has d³ configuration, so 3 unpaired electrons. $$\mu = \sqrt{3(3+2)} = \sqrt{15} = 3.87$$ BM. This is NOT between 4.4-5.2 BM. Incorrect.

Correct statements: B and C only.

The correct answer is Option 1: B, C only.

Get AI Help

Video Solution

video

Create a FREE account and get:

  • Free JEE Mains Previous Papers PDF
  • Take JEE Mains paper tests

JEE Quant Questions | JEE Quantitative Ability

JEE DILR Questions | LRDI Questions For JEE

JEE Verbal Ability Questions | VARC Questions For JEE

Free JEE Topicwise Questions

JEE Rotational MotionJEE Units & MeasurementsJEE Atomic StructureJEE GravitationJEE Periodic Table & PeriodicityJEE StatisticsJEE Inverse Trigonometric FunctionsJEE Magnetism & Magnetic MaterialsJEE Sequences & SeriesJEE MatricesJEE Alternating CurrentsJEE Carboxylic AcidsJEE Permutations & CombinationsJEE Work, Energy & PowerJEE Electromagnetic InductionJEE Electronic DevicesJEE d and f-Block ElementsJEE Chemical KineticsJEE Heat TransferJEE Three Dimensional GeometryJEE Magnetic Effects of CurrentJEE Hydrocarbons - AromaticJEE Electromagnetic WavesJEE Aldehydes & KetonesJEE Hydrocarbons - AlkanesJEE Applications of DerivativesJEE EquilibriumJEE Indefinite IntegrationJEE Chemical ThermodynamicsJEE ElectrochemistryJEE ProbabilityJEE BiomoleculesJEE Continuity & DifferentiabilityJEE Kinetic Theory of GasesJEE Vector AlgebraJEE Hydrocarbons - AlkynesJEE Differential EquationsJEE Current & ResistanceJEE Straight LinesJEE WavesJEE Redox ReactionsJEE Hydrocarbons - AlkenesJEE DeterminantsJEE SolutionsJEE Ray OpticsJEE Dual Nature of Matter & RadiationJEE Chemical Bonding & Molecular StructureJEE Complex NumbersJEE Sets, Relations & FunctionsJEE Electric Charges & FieldsJEE Laws of MotionJEE Fluid MechanicsJEE Basic Concepts in ChemistryJEE Trigonometric FunctionsJEE LimitsJEE Laws of ThermodynamicsJEE Kinematics - 2D MotionJEE p-Block Elements (Groups 13-18)JEE Simple Harmonic MotionJEE Electric Potential & CapacitanceJEE Coordination CompoundsJEE JEE 2D GeometryJEE CirclesJEE Definite IntegrationJEE EMF & Circuit AnalysisJEE Surface TensionJEE Atoms & NucleiJEE Laboratory Experiments - XIJEE Number SystemJEE Basic Principles of Organic ChemistryJEE Wave OpticsJEE Quadratic EquationsJEE Alcohols, Phenols & EthersJEE Organic Compounds with HalogensJEE DifferentiationJEE Conic SectionsJEE Nitrogen-Containing CompoundsJEE ElasticityJEE Practical Organic ChemistryJEE Kinematics - 1D MotionJEE Purification & CharacterisationJEE Binomial Theorem
Ask AI