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Question 32

While titration dilute HCl solution with aqueous NaOH, which of the following will not be required?

In an acid-base titration where a dilute $$\text{HCl}$$ solution is titrated with an aqueous $$\text{NaOH}$$ solution, we must measure the solutions accurately and detect the end-point with the help of an indicator. For accurate volume measurement we traditionally employ a burette for the titrant and a pipette for the analyte, both of which are supported on a stand with a clamp. A porcelain tile is commonly placed underneath the conical flask to provide a white background, making the indicator’s colour change more visible. The indicator most frequently chosen for a strong-acid versus strong-base titration is phenolphthalein because it changes sharply from colourless to faint pink in the pH range 8.0-10.0, exactly where the equivalence point lies for this titration. Distilled water is needed for rinsing the glassware to avoid introducing impurities that could affect the titre value. All these items are thus essential.

A Bunsen burner, however, is used for heating solutions or driving reactions that require elevated temperatures. Titrations of strong acids with strong bases are carried out at room temperature, so no heating device is necessary. Likewise, a measuring cylinder gives only approximate volumes, whereas titration demands the higher precision afforded by pipettes and burettes. Therefore a measuring cylinder is superfluous in this context. Because neither a Bunsen burner nor a measuring cylinder contributes anything crucial to the titration procedure, they are the items that will not be required.

Hence, the correct answer is Option D.

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