Join WhatsApp Icon JEE WhatsApp Group
Question 32

Given below are the two statements: one is labeled as Assertion (A) and the other is labeled as Reason (R).
Assertion (A): There is a considerable increase in covalent radius from $$N$$ to $$P$$. However from $$As$$ to $$Bi$$ only a small increase in covalent radius is observed.
Reason (R): covalent and ionic radii in a particular oxidation state increases down the group.
In the light of the above statement, choose the most appropriate answer from the options given below:

Assertion (A): "There is a considerable increase in covalent radius from $$N$$ to $$P$$. However from $$As$$ to $$Bi$$ only a small increase in covalent radius is observed."

This is TRUE. The covalent radii are approximately: N (70 pm), P (110 pm), As (121 pm), Sb (141 pm), Bi (148 pm). There is a large jump of about 40 pm from N to P (adding a new shell from period 2 to period 3). However, from As to Bi, the increases are much smaller because the addition of d-electrons (and f-electrons for Bi) causes poor shielding, which leads to a higher effective nuclear charge. This partially offsets the increase in radius due to additional shells.

Reason (R): "Covalent and ionic radii in a particular oxidation state increases down the group."

This is TRUE as a general trend. As we go down a group, new electron shells are added, so the atomic/ionic radii generally increase.

Relationship between A and R:

While R states that radii increase down the group (which is correct), it does not explain the specific observation in A -- namely, why the increase is large from N to P but small from As to Bi. The explanation for that requires the concept of poor shielding by d and f electrons, which is not mentioned in R.

Therefore, both (A) and (R) are true, but (R) is NOT the correct explanation of (A).

Get AI Help

Create a FREE account and get:

  • Free JEE Mains Previous Papers PDF
  • Take JEE Mains paper tests

JEE Quant Questions | JEE Quantitative Ability

JEE DILR Questions | LRDI Questions For JEE

JEE Verbal Ability Questions | VARC Questions For JEE

Free JEE Topicwise Questions

JEE Rotational MotionJEE Units & MeasurementsJEE Atomic StructureJEE GravitationJEE Periodic Table & PeriodicityJEE StatisticsJEE Inverse Trigonometric FunctionsJEE Magnetism & Magnetic MaterialsJEE Sequences & SeriesJEE MatricesJEE Alternating CurrentsJEE Carboxylic AcidsJEE Permutations & CombinationsJEE Work, Energy & PowerJEE Electromagnetic InductionJEE Electronic DevicesJEE d and f-Block ElementsJEE Chemical KineticsJEE Heat TransferJEE Three Dimensional GeometryJEE Magnetic Effects of CurrentJEE Hydrocarbons - AromaticJEE Electromagnetic WavesJEE Aldehydes & KetonesJEE Hydrocarbons - AlkanesJEE Applications of DerivativesJEE EquilibriumJEE Indefinite IntegrationJEE Chemical ThermodynamicsJEE ElectrochemistryJEE ProbabilityJEE BiomoleculesJEE Continuity & DifferentiabilityJEE Kinetic Theory of GasesJEE Vector AlgebraJEE Hydrocarbons - AlkynesJEE Differential EquationsJEE Current & ResistanceJEE Straight LinesJEE WavesJEE Redox ReactionsJEE Hydrocarbons - AlkenesJEE DeterminantsJEE SolutionsJEE Ray OpticsJEE Dual Nature of Matter & RadiationJEE Chemical Bonding & Molecular StructureJEE Complex NumbersJEE Sets, Relations & FunctionsJEE Electric Charges & FieldsJEE Laws of MotionJEE Fluid MechanicsJEE Basic Concepts in ChemistryJEE Trigonometric FunctionsJEE LimitsJEE Laws of ThermodynamicsJEE Kinematics - 2D MotionJEE p-Block Elements (Groups 13-18)JEE Simple Harmonic MotionJEE Electric Potential & CapacitanceJEE Coordination CompoundsJEE JEE 2D GeometryJEE CirclesJEE Definite IntegrationJEE EMF & Circuit AnalysisJEE Surface TensionJEE Atoms & NucleiJEE Laboratory Experiments - XIJEE Number SystemJEE Basic Principles of Organic ChemistryJEE Wave OpticsJEE Quadratic EquationsJEE Alcohols, Phenols & EthersJEE Organic Compounds with HalogensJEE DifferentiationJEE Conic SectionsJEE Nitrogen-Containing CompoundsJEE ElasticityJEE Practical Organic ChemistryJEE Kinematics - 1D MotionJEE Purification & CharacterisationJEE Binomial Theorem
Ask AI