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NTA JEE Main 24th February 2021 Shift 1 - Chemistry

For the following questions answer them individually

(A) $$HOCl + H_2O_2 \to H_3O^+ + Cl^- + O_2$$
(B) $$I_2 + H_2O_2 + 2OH^- \to 2I^- + 2H_2O + O_2$$
Choose the correct option.

$$Al_2O_3$$ was leached with alkali to get X. The solution of X on passing of gas Y, forms Z. X, Y and Z respectively are

Match List I with List II.

List I (Monomer Unit)List II (Polymer)
(a) Caprolactum(i) Natural rubber
(b) 2-Chloro-1,3-butadiene(ii) Buna-N
(c) Isoprene(iii) Nylon 6
(d) Acrylonitrile(iv) Neoprene

Choose the correct answer from the options given below:

Given below are two statements:
Statement I: Colourless cupric metaborate is reduced to cuprous metaborate in a luminous flame.
Statement II: Cuprous metaborate is obtained by heating boric anhydride and copper sulphate in a non-luminous flame.
In the light of the above statements, choose the most appropriate answer from the options given below.

A proton and a $$Li^{3+}$$ nucleus are accelerated by the same potential. If $$\lambda_{Li}$$ and $$\lambda_p$$ denote the de Broglie wavelengths of $$Li^{3+}$$ and proton respectively, then the value of $$\frac{\lambda_{Li}}{\lambda_p}$$ is $$x \times 10^{-1}$$. The value of $$x$$ is ______ (Rounded off to the nearest integer) [Mass of $$Li^{3+}$$ = 8.3 mass of proton]

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For the reaction $$A_g \to B_g$$, the value of the equilibrium constant at 300 K and 1 atm is equal to 100.0. The value of $$\Delta G^o$$ for the reaction at 300 K and 1 atm in J mol$$^{-1}$$ is $$-xR$$, where $$x$$ is ______ (Rounded off to the nearest integer) R = 8.31 J mol$$^{-1}$$ K$$^{-1}$$ and ln10 = 2.3

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The stepwise formation of $$[Cu(NH_3)_4]^{2+}$$ is given below:
$$Cu^{2+} + NH_3 \xrightleftharpoons{K_1} [Cu(NH_3)]^{2+}$$ 
$$[Cu(NH_3)]^{2+} + NH_3 \xrightleftharpoons{K_2} [Cu(NH_3)_2]^{2+}$$
$$[Cu(NH_3)_2]^{2+} + NH_3 \xrightleftharpoons{K_3} [Cu(NH_3)_3]^{2+}$$
$$[Cu(NH_3)_3]^{2+} + NH_3 \xrightleftharpoons{K_4} [Cu(NH_3)_4]^{2+}$$
The value of stability constants $$K_1$$, $$K_2$$, $$K_3$$ and $$K_4$$ are $$10^4$$, $$1.58 \times 10^3$$, $$5 \times 10^2$$ and $$10^2$$ respectively. The overall equilibrium constant for dissociation of $$[Cu(NH_3)_4]^{2+}$$ is $$x \times 10^{-12}$$. The value of $$x$$ is ______ (Rounded off to the nearest integer)

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At 1990 K and 1 atm pressure, there are equal number of $$Cl_2$$ molecules and Cl atoms in the reaction mixture. The value of $$K_p$$ for the reaction $$Cl_{2g} = 2Cl_g$$ under the above conditions is $$x \times 10^{-1}$$. The value of $$x$$ is ______ (Rounded off to the nearest integer)

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When 9.45 g of $$ClCH_2COOH$$ is added to 500 mL of water, its freezing point drops by 0.5°C. The dissociation constant of $$ClCH_2COOH$$ is $$x \times 10^{-3}$$. The value of $$x$$ is ______ (off to the nearest integer)
$$K_{f_{H_2O}} = 1.86$$ K kg mol$$^{-1}$$

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Gaseous cyclobutene isomerizes to butadiene in a first order process which has a 'K' value of $$3.3 \times 10^{-4}$$ s$$^{-1}$$ at 153°C. The time in minutes it takes for the isomerization to proceed 40% to completion at this temperature is ______ (Rounded off to the nearest integer)

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