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Question 68

The correct stability order of the following diazonium salts is 

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Stability Factors

  • -OCH₃ (Group A): A strong electron-donating group (+M effect). It provides the highest stability by shifting electron density toward the diazonium group.
  • No substitution (Group C): Acts as the baseline for comparison.
  • -CN (Group D): An electron-withdrawing group (-M, -I effect). It destabilizes the cation.
  • -NO₂ (Group B): A very strong electron-withdrawing group (-M, -I effect). It causes the greatest destabilization.

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