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The kinetic energy of an electron in the second Bohr orbit of a hydrogen atom is equal to $$\frac{h^2}{x \cdot m a_0^2}$$. The value of 10x is _________. ($$a_0$$ is radius of Bohr's orbit)
(Nearest integer)
[Given: $$\pi = 3.14$$]
Correct Answer: 3155
For an electron moving in the $$n^{\text{th}}$$ Bohr orbit of a hydrogen atom, two standard relations are used repeatedly:
1. (Coulomb’s law equals centripetal force) $$\frac{e^{2}}{4\pi\varepsilon_{0}r_{n}^{2}}=\frac{m v_{n}^{2}}{r_{n}}$$
2. (Bohr’s quantisation of angular momentum) $$m v_{n} r_{n}=n\frac{h}{2\pi}$$
Eliminating $$v_{n}$$ from these two equations gives the well-known expression for the radius of the $$n^{\text{th}}$$ orbit,
$$r_{n}=n^{2}a_{0},$$
where the Bohr radius $$a_{0}$$ is
$$a_{0}= \frac{\varepsilon_{0}h^{2}}{\pi m e^{2}}.$$
We need the kinetic energy in the second orbit ($$n=2$$). From mechanics,
$$\text{K.E.}=\frac{1}{2}m v_{n}^{2}.$$
First we find $$v_{n}^{2}$$ from the force balance. Using the first relation,
$$\frac{e^{2}}{4\pi\varepsilon_{0}r_{n}^{2}}=\frac{m v_{n}^{2}}{r_{n}} \;\;\Longrightarrow\;\; v_{n}^{2}= \frac{e^{2}}{4\pi\varepsilon_{0}m r_{n}}.$$
Now substitute $$r_{n}=n^{2}a_{0}$$:
$$v_{n}^{2}= \frac{e^{2}}{4\pi\varepsilon_{0}m n^{2}a_{0}}.$$
Hence the kinetic energy is
$$\text{K.E.}= \frac12 m v_{n}^{2} =\frac12 m\left(\frac{e^{2}}{4\pi\varepsilon_{0}m n^{2}a_{0}}\right) =\frac{e^{2}}{8\pi\varepsilon_{0} n^{2} a_{0}}.$$
To convert the factor $$\dfrac{e^{2}}{4\pi\varepsilon_{0}}$$ into a form containing $$h^{2}$$ and $$a_{0}$$, we use the definition of $$a_{0}$$ written above. Starting with
$$a_{0}= \frac{\varepsilon_{0}h^{2}}{\pi m e^{2}},$$
rearrange to obtain
$$e^{2}= \frac{\varepsilon_{0}h^{2}}{\pi m a_{0}} \;\;\Longrightarrow\;\; \frac{e^{2}}{4\pi\varepsilon_{0}} =\frac{h^{2}}{4\pi^{2} m a_{0}}.$$
Insert this expression into the kinetic‐energy formula:
$$\text{K.E.}= \frac{1}{2 n^{2} a_{0}} \left(\frac{e^{2}}{4\pi\varepsilon_{0}}\right) = \frac{1}{2 n^{2} a_{0}} \left(\frac{h^{2}}{4\pi^{2} m a_{0}}\right) =\frac{h^{2}}{8\pi^{2} n^{2} m a_{0}^{2}}.$$
For the second orbit, $$n=2\;$$ so $$n^{2}=4$$:
$$\text{K.E.}= \frac{h^{2}}{8\pi^{2}(4) m a_{0}^{2}} =\frac{h^{2}}{32\pi^{2} m a_{0}^{2}}.$$
This matches the required form $$\text{K.E.}= \frac{h^{2}}{x\,m a_{0}^{2}},$$ so
$$x = 32\pi^{2}.$$
Using $$\pi = 3.14$$ (as given),
$$\pi^{2}=3.14^{2}=9.8596,$$
$$x = 32 \times 9.8596 = 315.5072.$$
Now the question asks for $$10x$$ and its nearest integer value:
$$10x = 10 \times 315.5072 = 3155.072 \approx 3155.$$\
Hence, the correct answer is Option 3155.
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