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Question 34

The statement(s) that are correct about the species $$O^{2-}, F^-, Na^+$$ and $$Mg^{2+}$$. (A) All are isoelectronic (B) All have the same nuclear charge (C) $$O^{2-}$$ has the largest ionic radii (D) $$Mg^{2+}$$ has the smallest ionic radii. Choose the most appropriate answer from the options given below :

Species: $$O^{2-}, F^-, Na^+, Mg^{2+}$$.

(A) All are isoelectronic: All have 10 electrons. $$O^{2-}$$ (8+2=10), $$F^-$$ (9+1=10), $$Na^+$$ (11-1=10), $$Mg^{2+}$$ (12-2=10). Correct.

(B) All have the same nuclear charge: $$O$$ has 8 protons, $$F$$ has 9, $$Na$$ has 11, $$Mg$$ has 12. They have different nuclear charges. Incorrect.

(C) $$O^{2-}$$ has the largest ionic radius: For isoelectronic species, the one with the smallest nuclear charge has the largest radius. $$O^{2-}$$ has the smallest nuclear charge (8), so it has the largest ionic radius. Correct.

(D) $$Mg^{2+}$$ has the smallest ionic radius: $$Mg^{2+}$$ has the largest nuclear charge (12) among the isoelectronic species, so it has the smallest ionic radius. Correct.

Correct statements: (A), (C), and (D).

The correct answer is Option (3): (A), (C) and (D) only.

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