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A monochromatic light is incident on a hydrogen sample in ground state. Hydrogen atoms absorb a fraction of light and subsequently emit radiation of six different wavelengths. The frequency of incident light is $$x \times 10^{15}$$ Hz. The value of x is _______.
(Given $$h = 4.25 \times 10^{-15}$$ eVs)
Correct Answer: 3
When hydrogen atoms absorb light and subsequently emit radiation of 6 different wavelengths, we use the formula for number of spectral lines:
$$\text{Number of lines} = \frac{n(n-1)}{2}$$
Setting this equal to 6:
$$\frac{n(n-1)}{2} = 6 \implies n(n-1) = 12 \implies n = 4$$
So the hydrogen atoms are excited from the ground state ($$n = 1$$) to $$n = 4$$.
Energy required:
$$E = 13.6\left(\frac{1}{1^2} - \frac{1}{4^2}\right) = 13.6\left(1 - \frac{1}{16}\right) = 13.6 \times \frac{15}{16}$$
$$E = \frac{204}{16} = 12.75 \text{ eV}$$
Frequency of incident light:
$$f = \frac{E}{h} = \frac{12.75}{4.25 \times 10^{-15}} = 3 \times 10^{15} \text{ Hz}$$
Therefore, $$x = 3$$.
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