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P-T diagram of an ideal gas having three different densities $$\rho_1, \rho_2, \rho_3$$ (in three different cases) is shown in the figure. Which of the following is correct:
For an ideal gas,
$$PV=nRT$$
Also density,
$$\rho=\frac{m}{V}$$
and
$$n=\frac{m}{M}$$
So ideal gas law becomes
$$P=\frac{\rho}{M}RT$$
or
$$P=\left(\frac{\rho R}{M}\right)T$$
This is the equation of a straight line in a P-T graph, whose slope is
$$slope=\frac{\rho R}{M}$$
Since R and molar mass M are constant, slope is directly proportional to density:
$$slope∝ρ$$
From the graph, line corresponding to $$\rho_1$$ has greatest slope, then
$$\rho_2\ then\ \rho_3$$
Hence,
$$\rho_1>\rho_2>\rho_3$$
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