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NTA JEE Mains 04th April 2024 Shift 2 - Chemistry

For the following questions answer them individually

Choose the Incorrect Statement about Dalton's Atomic Theory

Given below are two statements: Statement I: The correct order of first ionization enthalpy values of Li, Na, F and Cl is $$Na < Li < Cl < F$$. Statement II: The correct order of negative electron gain enthalpy values of Li, Na, F and Cl is $$Na < Li < F < Cl$$. In the light of the above statements, choose the correct answer from the options given below:

The correct statement/s about Hydrogen bonding is/are: A. Hydrogen bonding exists when H is covalently bonded to the highly electronegative atom. B. Intermolecular H bonding is present in o-nitrophenol. C. Intramolecular H bonding is present in HF. D. The magnitude of H bonding depends on the physical state of the compound. E. H-bonding has powerful effect on the structure and properties of compounds. Choose the correct answer from the options given below:

For a strong electrolyte, a plot of molar conductivity against (concentration)$$^{1/2}$$ is a straight line, with a negative slope, the correct unit for the slope is:

Fuel cell, using hydrogen and oxygen as fuels: A. has been used in spaceship, B. has an efficiency of 40% to produce electricity, C. uses aluminum as catalysts, D. is eco-friendly, E. is actually a type of Galvanic cell only. Choose the correct answer from the options given below:

$$2.7$$ kg of each of water and acetic acid are mixed. The freezing point of the solution will be $$-x°C$$. Consider the acetic acid does not dimerise in water, nor dissociates in water. $$x =$$ ______ (nearest integer) [Given: Molar mass of water $$= 18$$ g mol$$^{-1}$$, acetic acid $$= 60$$ g mol$$^{-1}$$, $$K_f$$ H$$_2$$O: $$1.86$$ K kg mol$$^{-1}$$, $$K_f$$ acetic acid: $$3.90$$ K kg mol$$^{-1}$$, freezing point: H$$_2$$O $$= 273$$ K, acetic acid $$= 290$$ K]

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Consider the following reaction, the rate expression of which is given below: 

$$A + B \rightarrow C$$, rate$$ = k[A]^{1/2}[B]^{1/2}$$.
The reaction is initiated by taking concentration of $$1$$M of $$A$$ and $$B$$ each. If the rate constant $$(k)$$ is $$4.6 \times 10^{-2}$$ s$$^{-1}$$, then the time taken for $$A$$ to become $$0.1$$M is ______ sec. (nearest integer)

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A first row transition metal with highest enthalpy of atomisation, upon reaction with oxygen at high temperature forms oxides of formula $$M_2O_n$$ (where $$n = 3, 4, 5$$). The 'spin-only' magnetic moment value of the amphoteric oxide from the above oxides is ______ BM (nearest integer). (Given atomic number: Sc: 21, Ti: 22, V: 23, Cr: 24, Mn: 25, Fe: 26, Co: 27, Ni: 28, Cu: 29, Zn: 30)

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