For the following questions answer them individually
Among statements (a) - (d), the correct ones are:
(a) Decomposition of hydrogen peroxide gives di-oxygen.
(b) Like hydrogen peroxide, compounds, such as KClO$$_3$$, Pb(NO$$_3$$) and NaNO$$_3$$ when heated liberate di-oxygen.
(c) 2-Ethylanthraquinone is useful for the industrial preparation of hydrogen peroxide.
(d) Hydrogen peroxide is used for the manufacture of sodium perborate.
The correct order of stability for the following alkoxides is:
A chromatography column, packed with silica gel as stationary phase, was used to separate a mixture of compounds consisting of (A) benzanilide (B) aniline and (C) acetophenone. When the column is eluted with a mixture of solvents, hexane:ethyl acetate (20 : 80), the sequence of obtained compounds is:
Two open beakers one containing a solvent and the other containing a mixture of that solvent with a non volatile solute are together sealed in a container. Over time:
The equation that is incorrect is:
For the reaction $$2H_2(g) + 2NO(g) \rightarrow N_2(g) + 2H_2O(g)$$ the observed rate expression is, rate $$= k_f[NO]^2[H_2]$$. The rate expression for the reverse reaction is:
The refining method used when the metal and the impurities have low and high melting temperatures, respectively, is
In the following reactions, products (A) and (B), respectively, are:
NaOH + Cl$$_2$$ $$\rightarrow$$ (A) + side products (hot and conc.)
Ca(OH)$$_2$$ + Cl$$_2$$ $$\rightarrow$$ (B) + side products (dry)
The number of possible optical isomers for the complexes MA$$_2$$B$$_2$$ with sp$$^3$$ and dsp$$^2$$ hybridized metal atom, respectively, is:
Note: A and B are unidentate neutral and unidentate monoanionic ligands, respectively.
Among the statements (a) - (d), the incorrect ones are:
(a) Octahedral Co(III) complexes with strong field ligands have very high magnetic moments
(b) When $$\Delta_0 < P$$, the d-electron configuration of Co(III) in an octahedral complex is $$t_{eg}^4 e_g^2$$
(c) Wavelength of light absorbed by [Co(en)$$_3$$]$$^{3+}$$ is lower than that of [CoF$$_6$$]$$^{3-}$$
(d) If the $$\Delta_0$$ for an octahedral complex of Co(III) is 18,000 cm$$^{-1}$$, the $$\Delta_t$$ for its tetrahedral complex with the same ligand will be 16,000 cm$$^{-1}$$.