For the following questions answer them individually
Given below are two statements : one is labelled as Assertion and the other is labelled as Reason.
Assertion: The ionic radii of $$O^{2-}$$ and $$Mg^{2+}$$ are same.
Reason: Both $$O^{2-}$$ and $$Mg^{2+}$$ are isoelectronic species.
Based upon VSEPR theory, match the shape (geometry) of the molecules in List-I with the molecules in List-II
| List-I (Shape) | List-II (Molecules) |
|---|---|
| A T-shaped | I. $$XeF_4$$ |
| B Trigonal planar | II. $$SF_4$$ |
| C Square planar | III. $$ClF_3$$ |
| D See-saw | IV. $$BF_3$$ |
Match List - I with List - II.
| List-I | List-II |
|---|---|
| (A) Spontaneous process | (I) $$\Delta H < 0$$ |
| (B) Process with $$\Delta P = 0, \Delta T = 0$$ | (II) $$\Delta G_{T,P} < 0$$ |
| (C) $$\Delta H_{reaction}$$ | (III) Isothermal and isobaric process |
| (D) Exothermic Process | (IV) [Bond energies in reactants] - [Bond energies in products] |
Choose the correct answer from the options given below
Addition of $$H_2SO_4$$ to $$BaO_2$$ produces
$$BeCl_2$$ reacts with $$LiAlH_4$$ to give
Match List - I with List - II.
| List-I (Si-Compounds) | List-II (Si-Polymeric/Other Products) |
|---|---|
| A $$(CH_3)_4Si$$ | I Chain Silicone |
| B $$(CH_3)Si(OH)_3$$ | II Dimeric Silicone |
| C $$(CH_3)_2Si(OH)_2$$ | III Silane |
| D $$(CH_3)_3Si(OH)$$ | IV 2D-Silicone |
Choose the correct answer from the options given below
L-isomer of a compound 'A'($$C_4H_8O_4$$) gives a positive test with $$[Ag(NH_3)_2]^+$$. Treatment of 'A' with acetic anhydride yields triacetate derivative. Compound 'A' produces an optically active compound (B) and an optically inactive compound (C) on treatment with bromine water and $$HNO_3$$ respectively. Compound (A) is :
Given below are two Statements :
Statement I : Classical smog occurs in cool humid climate. It is a reducing mixture of smoke, fog and sulphur dioxide.
Statement II : Photochemical smog has components, ozone, nitric oxide, acrolein, formaldehyde, PAN etc.
In the light of the above statements, choose the most appropriate answer from the options given below.
Given below are two statements : one is labelled as Assertion and the other is labelled as Reason.
Assertion: At $$10°$$C, the density of a $$5$$ M solution of KCl [atomic masses of K & Cl are $$39$$ & $$35.5$$ g mol$$^{-1}$$ respectively], is 'x' g mL$$^{-1}$$. The solution is cooled to $$-21°$$C. The molality of the solution will remain unchanged.
Reason: The molality of a solution does not change with temperature as mass remains unaffected with temperature.
In the light of the above statements, choose the most appropriate answer from the options given below.
Match List - I with List - II.
| List-I | List-II |
|---|---|
| A Lyophilic colloid | I Liquid-liquid colloid |
| B Emulsion | II Protective colloid |
| C Positively charged colloid | III $$FeCl_3 + NaOH$$ |
| D Negatively charged colloid | IV $$FeCl_3$$ + hot water |
Choose the correct answer from the options given below