NTA JEE Main 27th June 2022 Shift 1

Instructions

For the following questions answer them individually

NTA JEE Main 27th June 2022 Shift 1 - Question 31


Given below are two statements : one is labelled as Assertion and the other is labelled as Reason.
Assertion: The ionic radii of $$O^{2-}$$ and $$Mg^{2+}$$ are same.
Reason: Both $$O^{2-}$$ and $$Mg^{2+}$$ are isoelectronic species.

NTA JEE Main 27th June 2022 Shift 1 - Question 32


Based upon VSEPR theory, match the shape (geometry) of the molecules in List-I with the molecules in List-II

List-I (Shape)List-II (Molecules)
A T-shapedI. $$XeF_4$$
B Trigonal planarII. $$SF_4$$
C Square planarIII. $$ClF_3$$
D See-sawIV. $$BF_3$$

NTA JEE Main 27th June 2022 Shift 1 - Question 33


Match List - I with List - II.

List-IList-II
(A) Spontaneous process(I) $$\Delta H < 0$$
(B) Process with $$\Delta P = 0, \Delta T = 0$$(II) $$\Delta G_{T,P} < 0$$
(C) $$\Delta H_{reaction}$$(III) Isothermal and isobaric process
(D) Exothermic Process(IV) [Bond energies in reactants] - [Bond energies in products]

Choose the correct answer from the options given below

NTA JEE Main 27th June 2022 Shift 1 - Question 34


Addition of $$H_2SO_4$$ to $$BaO_2$$ produces

NTA JEE Main 27th June 2022 Shift 1 - Question 35


$$BeCl_2$$ reacts with $$LiAlH_4$$ to give

NTA JEE Main 27th June 2022 Shift 1 - Question 36


Match List - I with List - II.

List-I (Si-Compounds)List-II (Si-Polymeric/Other Products)
A $$(CH_3)_4Si$$I Chain Silicone
B $$(CH_3)Si(OH)_3$$II Dimeric Silicone
C $$(CH_3)_2Si(OH)_2$$III Silane
D $$(CH_3)_3Si(OH)$$IV 2D-Silicone

Choose the correct answer from the options given below

NTA JEE Main 27th June 2022 Shift 1 - Question 37


L-isomer of a compound 'A'($$C_4H_8O_4$$) gives a positive test with $$[Ag(NH_3)_2]^+$$. Treatment of 'A' with acetic anhydride yields triacetate derivative. Compound 'A' produces an optically active compound (B) and an optically inactive compound (C) on treatment with bromine water and $$HNO_3$$ respectively. Compound (A) is :

NTA JEE Main 27th June 2022 Shift 1 - Question 38


Given below are two Statements :
Statement I : Classical smog occurs in cool humid climate. It is a reducing mixture of smoke, fog and sulphur dioxide.
Statement II : Photochemical smog has components, ozone, nitric oxide, acrolein, formaldehyde, PAN etc.
In the light of the above statements, choose the most appropriate answer from the options given below.

NTA JEE Main 27th June 2022 Shift 1 - Question 39


Given below are two statements : one is labelled as Assertion and the other is labelled as Reason.
Assertion: At $$10°$$C, the density of a $$5$$ M solution of KCl [atomic masses of K & Cl are $$39$$ & $$35.5$$ g mol$$^{-1}$$ respectively], is 'x' g mL$$^{-1}$$. The solution is cooled to $$-21°$$C. The molality of the solution will remain unchanged.
Reason: The molality of a solution does not change with temperature as mass remains unaffected with temperature.
In the light of the above statements, choose the most appropriate answer from the options given below.

NTA JEE Main 27th June 2022 Shift 1 - Question 40


Match List - I with List - II.

List-IList-II
A Lyophilic colloidI Liquid-liquid colloid
B EmulsionII Protective colloid
C Positively charged colloidIII $$FeCl_3 + NaOH$$
D Negatively charged colloidIV $$FeCl_3$$ + hot water

Choose the correct answer from the options given below

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