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NTA JEE Main 12th January 2019 Shift 2 - Chemistry

For the following questions answer them individually

Given:
(i) C(graphite) + O$$_2$$(g) $$\to$$ CO$$_2$$(g); $$\Delta_r H^{\ominus} = x$$ kJ mol$$^{-1}$$,
(ii) C(graphite) + $$\frac{1}{2}$$O$$_2$$(g) $$\to$$ CO(g); $$\Delta_r H^{\ominus} = y$$ kJ mol$$^{-1}$$,
(iii) CO(g) + $$\frac{1}{2}$$O$$_2$$(g) $$\to$$ CO$$_2$$(g); $$\Delta_r H^{\ominus} = z$$ kJ mol$$^{-1}$$.
Based on the above thermochemical equations, find out which one of the following algebraic relationships is correct?

Molecules of benzoic acid ($$C_6H_5COOH$$) dimerise in 30 g of benzene. 'w' g of benzoic acid shows a depression in freezing point equal to 2 K. If the percentage association of the acid to form dimer in the solution is 80, then w is: (Given that $$K_f = 5$$ K mol$$^{-1}$$, molar mass of benzoic acid = 122 g mol$$^{-1}$$)

For a reaction, consider the plot of ln k versus 1/T given in the figure. If the rate constant of this reaction at 400 K is $$10^{-5} s^{-1}$$, then the rate constant at 500 K is:

image

Among the following, the false statement is:

The two monomers for the synthesis of nylon 6,6 are

The correct statement(s) among I to III with respect to potassium ions that are abundant within the cell fluids, is/are: I. They activate many enzymes. II. They participate in the oxidation of glucose to produce ATP. III. Along with sodium ions, they are responsible for the transmission of nerve signals.