NTA JEE Mains 24th Jan 2025 Shift 2 - Chemistry

For hydrogen atom, the orbital/s with lowest energy is/are:$$\text{ (A) } 4s \text{ (B) } 3p_x \text{ (C) } 3d_{x^2-y^2} \text{ (D) } 3d_{z^2} \text{ (E) } 4p_z$$  Choose the correct answer from the options given below:

Match List - I with List - II.

Choose the correct answer from the options given below :

Given below are two statements : Statement (I): Experimentally determined oxygen-oxygen bond lengths in the $$ O_3 $$ are found to be same and the bond length is greater than that of a $$O = O$$ (double bond) but less than that of a single $$(O - O)$$ bond. Statement (II) : The strong lone pair-lone pair repulsion between oxygen atoms is solely responsible for the fact that the bond length in ozone is smaller than that of a double bond $$(O = O)$$ but more than that of a single bond $$(O - O)$$. In the light of the above statements, choose the correct answer from the options given below :

When Ethane-1,2-diamine is added progressively to an aqueous solution of Nickel (II) chloride, the sequence of colour change observed will be :

Given below are two statements :
Statement (I) : The first ionization energy of Pb is greater than that of Sn .
Statement (II) : The first ionization energy of Ge is greater than that of Si .
In the light of the above statements, choose the correct answer from the options given below :

$$\text{Identify correct statement/s : }(A) -OCH_3 \text{ and } -NHCOCH_3 \text{ are activating groups. } (B)-CN \text{ and } -OH \text{ are meta directing groups. } (C) -CN \text{ and } -SO_3H$$ are meta directing groups.  $$(D)$$ Activating groups act as ortho- and para-directing groups.  $$(E)$$ Halides are activating groups. Choose the correct answer from the options given below:

Based on the data given below: $$\begin{aligned}E^\circ_{\text{Cr}_2\text{O}_7^{2-}/\text{Cr}^{3+}} &= 1.33 \text{V} &E^\circ_{\text{Cl}_2/\text{Cl}^-} &= 1.36\ \text{V} \\E^\circ_{\text{MnO}_4^-/\text{Mn}^{2+}} &= 1.51 \text{V} &E^\circ_{\text{Cr}^{3+}/\text{Cr}} &= -0.74\ \text{V}\end{aligned}$$ the strongest reducing agent is:

$$\text{For the reaction, } H_2(g) + I_2(g) \rightleftharpoons 2HI(g),$$  Attainment of equilibrium is predicted correctly by:

Find the compound ' A ' from the following reaction sequences. 

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The elemental composition of a compound is  $$54.2\%C,\ 9.2\%H$$  and  $$36.6\%O.$$ If the molar mass of the compound is  $$132\ \text{g mol}^{-1},$$ the molecular formula of the compound is: [Given: Relative atomic masses  C:H:O = 12:1:16]

{The conditions and consequence that favours the  $$t_{2gg} e_g^1$$  configuration in a metal complex are:

In the given structure, the number of $$sp \text{ and } sp^2 $$ hybridized carbon atoms present respectively are:

Given below are two statements :
In the light of the above statements, choose the correct answer from the options given below :

Choose the correct answer from the options given below :

The structure of the major product formed in the following reaction is :

For reaction
The correct order of set of reagents for the above conversion is :

The successive 5 ionisation energies of an element are 800, 2427, 3658, 25024 and 32824 kJ/mol, respectively. By using the above values predict the group in which the above element is present:

Choose the correct answer from the options given below :

Which of the following mixing of 1 M base and 1 M acid leads to the largest increase in temperature?

$$S(g) + \frac{3}{2}O_2(g) \rightarrow SO_3(g) + 2x\,\text{kcal} \\SO_2(g) + \frac{1}{2}O_2(g) \rightarrow SO_3(g) + y\,\text{kcal}\\\text{The heat of formation of } SO_2(g) \text{ is given by:}$$

In Carius method of estimation of halogen, $$0.25\,g$$  of an organic compound gave  $$0.15\,g$$  of silver bromide $$(AgBr).$$ The percentage of Bromine in the organic compound is $$\underline{\hspace{2cm}}\times 10^{-1}$$ (Nearest integer). }[ Given: Molar mass of Ag is 108 and Br is 80 g  $$mol^{-1}$$]

The observed and normal molar masses of compound  $$MX_2$$ are  $$65.6$$  and  $$164$$  respectively. The percent degree of ionisation of  $$MX_2$$  is  $$\underline{\hspace{2cm}}\%.$$  (Nearest integer)

Consider a complex reaction taking place in three steps with rate constants $$k_1,\; k_2 \text{ and } k_3$$ respectively. The overall rate constant  $$k$$ is given by $$k=\sqrt{\frac{k_1k_3}{k_2}}$$. If the activation energies of the three steps are $$60,\;30$$  and  $$10\,kJ\,mol^{-1}$$  respectively, then the overall energy of activation in  $$kJ\,mol^{-1}$$ is  $$\underline{\hspace{2cm}}.$$ (Nearest integer)

The possible number of stereoisomers for 5-phenylpent -4-en-2-ol is $$\underline{\hspace{2cm}}.$$

The hydrocarbon  $$(X)$$  with molar mass  $$80\,g\,mol^{-1}$$ and  $$90\% $$ carbon has $$\underline{\hspace{2cm}}$$  degree of unsaturation.