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NTA JEE Mains 23rd Jan 2025 Shift 2 - Chemistry

For the following questions answer them individually

Consider the following reactions $$K_{2}Cr_{2}O_{7}\xrightarrow[-H_{2}O]{KOH}[A]\xrightarrow[-H_{2}O]{H_{2}SO_{4}}[B]+K_{2}SO_{4}$$ The products [A] and [B], respectively are :

Consider the reaction $$X_{2}Y(g)=X_{2}(g)+\frac{1}{2}Y_{2}(g)$$ The equation representing correct relationship between the degree of dissociation (x) of $$X_{2}Y(g)$$ with its equilibrium constant Kp is ______ . Assume x to be very very small.

Given below are two statements : Consider the following reaction

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Given below are two statements : Statement (I) : For a given shell, the total number of allowed orbitals is given by $$n^{2}$$. Statement (II) : For any subshell, the spatial orientation of the orbitals is given by -l to +l values including zero. In the light of the above statements, choose the correct answer from the options given below :

Standard electrode potentials for a few half cells are mentioned below :
$$E_{Cu^{2+}/Cu}^{\circ}=0.34 V,E_{Zn^{2+}/Zn}^{\circ}=-0.76 V\\E_{Ag^{+}/Ag}^{\circ}=0.80 V,E_{Mg^{2+}/Mg}^{\circ}=-2.37 V$$ Which one of the following cells gives the most negative value of $$\Delta G^{\circ}$$ ?

Given below are two statements about X-ray spectra of elements : Statement (I) : A plot of $$\sqrt{v}$$($$\upsilon$$ = frequency of -rays emitted) vs atomic mass is a straight line. Statement (II) : A plot of $$\upsilon(\upsilon$$ = frequency of -rays emitted) vs atomic number is a straight line. In the light of the above statements, choose the correct answer from the options given below :

Given below are two statements : Statement (I) : The boiling points of alcohols and phenols increase with increase in the number of C-atoms. Statement (II) : The boiling points of alcohols and phenols are higher in comparison to other class of compounds such as ethers, haloalkanes. In the light of the above statements, choose the correct answer from the options given below :

Consider a binary solution of two volatile liquid components 1 and 2.$$x_{1}$$ and $$y_{1}$$ are the mole fractions of component 1 in liquid and vapour phase, respectively. The slope and intercept of the linear plot of $$\frac{1}{x_{1}}$$ vs $$\frac{1}{y_{1}}$$ are given respectively as:

Match List - I with List - II.

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Choose the correct answer from the options given below :

Identify the coordination complexes in which the central metal ion has $$d^{4}$$ configuration.

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Choose the correct answer from the options given below :

When 81.0 g of aluminium is allowed to react with 128.0 g of oxygen gas, the mass of aluminium oxide produced in grams is_______ - (Nearest integer) Given : Molar mass of Al is 27.0 g $$mol^{-1}$$ Molar mass of O is 16.0 g $$mol^{-1}$$.

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The bond dissociation enthalpy of $$X_2$$ (ΔHbond) calculated from the given data is ____________ $$kJmol^{-1}$$. (Nearest integer)

  • $$M^+X^-$$(s) → $$M^+$$(g) +$$X^-$$(g)                ΔH°lattice = 800 $$kJmol^{-1}$$
  • M(s) → M(g)                                                ΔH°sub = 100 $$kJmol^{-1}$$
  • M(g) → $$M^+(g)+e^{_-}(g)$$                       ΔHi = 500 $$kJmol^{-1}$$
  • X(g) → $$e^-(g)→X^-(g)$$                           ΔH°eg = -300 $$kJmol^{-1}$$
  • M(g) + ½X2(g) → $$M^+X^-$$(s)                   ΔH°f = -400 $$kJmol^{-1}$$

[Given: ($$M^+X^-$$) is a pure ionic compound and X forms a diatomic molecule ($$X_2$$) in gaseous state]

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