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NTA JEE Main 6th April 2023 Shift 1 - Chemistry

For the following questions answer them individually

For a concentrated solution of a weak electrolyte ($$K_{eq}$$ = equilibrium constant) A$$_2$$B$$_3$$ of concentration 'C', the degree of dissociation '$$\alpha$$' is

Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R.
Assertion A: Loss of electron from hydrogen atom results in nucleus of ~$$1.5 \times 10^{-3}$$ pm size.
Reason R: Proton H$$^+$$ always exists in combined form.
In the light of the above statements, choose the most appropriate answer from the options given below:

Match List-I with List-II.
List-I (Element detected)   List-II (Reagent used/Product formed)
A. Nitrogen                         I.      Na$$_2$$FeCN$$_5$$NO
B. Sulphur                           II.     AgNO$$_3$$
C. Phosphorus                   III.    Fe$$_4$$FeCN$$_{6_{3}}$$
D. Halogen                          IV.   NH$$_{4_{2}}$$MoO$$_4$$

A compound is formed by two elements X and Y. The element Y forms cubic close packed arrangement and those of element X occupy one third of the tetrahedral voids. What is the formula of the compound?

Match List I with List II
LIST I - Enzymatic reaction                           LIST II - Enzyme
A. Sucrose $$\rightarrow$$ Glucose and Fructose            I. Zymase
B. Glucose $$\rightarrow$$ ethyl alcohol and CO$$_2$$             II. Pepsin
C. Starch $$\rightarrow$$ Maltose                                        III. Invertase
D. Proteins $$\rightarrow$$ Amino acids                             IV. Diastase

Match List I with List II
List I (Oxide)   List II (Type of bond)
A. N$$_2$$O$$_4$$              I. 1 N=O bond
B. NO$$_2$$                II. 1 N-O-N bond
C. N$$_2$$O$$_5$$              III. 1 N-N bond
D. N$$_2$$O                IV. 1 N=N/N$$\equiv$$N bond

Match List-I with List-II.
List-I (Name of reaction)                  List-II (Reagent used)
A. Hell-Volhard Zelinsky reaction       I. NaOH + I$$_2$$
B. Iodoform reaction                            II. (i) CrO$$_2$$Cl$$_2$$, CS$$_2$$ (ii) H$$_2$$O
C. Etard reaction                                   III. (i) Br$$_2$$/red phosphorus (ii) H$$_2$$O
D. Gatterman-Koch reaction               IV. CO, HCl, anhyd. AlCl$$_3$$

Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R.
Assertion A: The spin only magnetic moment value for Fe(CN)$$_6^{3-}$$ is 1.74 BM, whereas for [Fe(H$$_2$$O)$$_6$$]$$^{3+}$$ is 5.92 BM.
Reason B: In both complexes, Fe is present in +3 oxidation state.
In the light of the above statements, choose the correct answer from the options given below:

For the reaction

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The correct statement is

Match List I and List II
List I (Vitamin)               List II (Deficiency disease)
A. Vitamin A                     I. Beri-Beri
B. Thiamine                      II. Cheilosis
C. Ascorbic acid              III. Xerophthalmia
D. Riboflavin                     IV. Scurvy
Choose the correct answer from the options given below

Consider the graph of Gibbs free energy G vs extent of reaction. The number of statement/s from the following which are true with respect to points (a), (b) and (c) is ______

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A. Reaction is spontaneous at (a) and (b)
B. Reaction is at equilibrium at point (b) and non-spontaneous at point (c)
C. Reaction is spontaneous at (a) and non-spontaneous at (c)
D. Reaction is non-spontaneous at (a) and (b)

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Mass of Urea NH$$_2$$CONH$$_2$$ required to be dissolved in 1000 g of water in order to reduce the vapour pressure of water by 25% is ______ g. (Nearest integer)
Given: Molar mass of N, C, O and H are 14, 12, 16 and 1 g mol$$^{-1}$$ respectively.

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For the adsorption of hydrogen on platinum, the activation energy is 30 kJ mol$$^{-1}$$ and for the adsorption of hydrogen on nickel, the activation energy is 41.4 kJ mol$$^{-1}$$. The logarithm of the ratio of the rates of chemisorption on equal areas of the metals at 300 K is ______ (Nearest integer)
Given: ln10 = 2.3, R = 8.3 J K$$^{-1}$$ mol$$^{-1}$$

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