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NTA JEE Main 4th September 2020 Shift 1 - Chemistry

For the following questions answer them individually

The intermolecular potential energy for the molecules A, B, C and D given below suggests that:

For one mole of an ideal gas, which of these statements must be true?
(a) Internal energy (U) and enthalpy (H) each depends on temperature.
(b) Compressibility factor Z is not equal to 1
(c) $$C_{P,m} - C_{V,m} = R$$
(d) $$dU = C_v dT$$ for any process

Identify the incorrect statement from the options below for the above cell:

$$E^0_{Cu^{2+}|Cu} = +0.34$$ V,
$$E^0_{Zn^{2+}|Zn} = -0.76$$ V

Match the following:
(i) Foam            (a) smoke
(ii) Gel              (b) cell fluid
(iii) Aerosol       (c) jellies
(iv) Emulsion     (d) rubber
                          (e) froth
                          (f) milk

Among statements (a) - (d), the correct ones are:
(a) Lime stone is decomposed to CaO during the extraction of iron from its oxides.
(b) In the extraction of silver, silver is extracted as an anionic complex.
(c) Nickel is purified by Mond's process.
(d) Zr and Ti are purified by Van Arkel method.

The pair in which both the species have the same magnetic moment (spin only) is:

An organic compound (A) (molecular formula $$C_6H_{12}O_2$$) was hydrolysed with dil. $$H_2SO_4$$ to give a carboxylic acid (B) and an alcohol (C). 'C' gives white turbidity immediately when treated with anhydrous $$ZnCl_2$$ and conc. HCl. The organic compound (A) is:

A 20.0 mL solution containing 0.2 g impure $$H_2O_2$$ reacts completely with 0.316 g of $$KMnO_4$$ in acid solution. The purity of $$H_2O_2$$ (in %) is __________ (mol. wt. of $$H_2O_2$$ = 34; mol. wt. of $$KMnO_4$$ = 158)

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At 300 K, the vapour pressure of a solution containing 1 mole of n-hexane and 3 moles of n-heptane is 550 mm of Hg. At the same temperature, if one more mole of n-heptane is added to this solution, the vapour pressure of the solution increases by 10 mm of Hg. What is the vapour pressure in mmHg of n-heptane in its pure state?

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