NTA JEE Main 31st January 2023 Shift 1 - Chemistry

Which transition in the hydrogen spectrum would have the same wavelength as the Balmer type transition from n = 4 to n = 2 of He$$^+$$ spectrum

The correct increasing order of the ionic radii is

Match List I with List II
List I   List II
A. XeF$$_4$$   I. See-saw
B. SF$$_4$$   II. Square planar
C. NH$$_4^+$$   III. Bent T-shaped
D. BrF$$_3$$   IV. Tetrahedral
Choose the correct answer from the options given below:

$$H_2O_2$$ acts as a reducing agent in

Match items of column I and II

Choose the correct set of reagents for the following conversion
trans Ph - CH = CH - CH$$_3$$ $$\rightarrow$$ cis Ph - CH = CH - CH$$_3$$

Which one of the following statements is correct for electrolysis of brine solution?

Adding surfactants in non polar solvent, the micelles structure will look like
(a)

(b)

(c)

(d)

The methods NOT involved in concentration of ore are
(A) Liquation
(B) Leaching
(C) Electrolysis
(D) Hydraulic washing
(E) Froth floatation
Choose the correct answer from the options given below:

Identify X, Y and Z in the following reaction. (Equation not balanced)
$$ClO^. + NO_2 \rightarrow X \xrightarrow{H_2O} Y + Z$$

When Cu$$^{2+}$$ ion is treated with KI, a white precipitate, X appears in solution. The solution is titrated with sodium thiosulphate, the compound Y is formed. X and Y respectively are

The correct order of basicity of oxides of vanadium is

Nd$$^{2+}$$ = ______

Cobalt chloride when dissolved in water forms pink colored complex X which has octahedral geometry. This solution on treating with conc HCl forms deep blue complex, Y which has a Z geometry. X, Y and Z, respectively, are

The correct order of melting point of dichlorobenzenes is

An organic compound 'A' with empirical formula C$$_6$$H$$_6$$O gives sooty flame on burning. Its reaction with bromine solution in low polarity solvent results in high yield of B. B is

Consider the following reaction
Propanal + Methanal $$\xrightarrow{(i)$$ dil. NaOH $$}{\xrightarrow{(ii) \Delta \; (iii)$$ NaCN $$\; (iv) \; H_3O^+}}$$ Product B (C$$_5$$H$$_8$$O$$_3$$)
The correct statement for product B is. It is

Which of the following artificial sweeteners has the highest sweetness value in comparison to cane sugar?

A protein 'X' with molecular weight of 70,000 u, on hydrolysis gives amino acids. One of these amino acid is

On complete combustion, 0.492 g of an organic compound gave 0.792 g of CO$$_2$$. The % of carbon in the organic compound is (Nearest integer)

Zinc reacts with hydrochloric acid to give hydrogen and zinc chloride. The volume of hydrogen gas produced at STP from the reaction of 11.5 g of zinc with excess HCl is L (Nearest integer)
(Given: Molar mass of Zn is 65.4 g mol$$^{-1}$$ and Molar volume of H$$_2$$ at STP = 22.7 L)

The enthalpy change for the conversion of $$\dfrac{1}{2}$$Cl$$_2$$(g) to Cl$$^-$$(aq) is (-) ______ kJmol$$^{-1}$$ (Nearest integer)
Given: $$\Delta_{dis}H^0_{Cl_2(g)} = 240$$ kJmol$$^{-1}$$
$$\Delta_{eg}H^o_{Cl(g)} = -350$$ kJmol$$^{-1}$$
$$\Delta_{hyd}H^o_{Cl^-(g)} = -380$$ kJmol$$^{-1}$$

For reaction: $$SO_2(g) + \dfrac{1}{2}O_2(g) \rightleftharpoons SO_3(g)$$ $$K_P = 2 \times 10^{12}$$ at 27°C and 1 atm pressure. The $$K_c$$ for the same reaction is ______ $$\times 10^{13}$$. (Nearest integer)
(Given $$R = 0.082$$ L atm K$$^{-1}$$ mol$$^{-1}$$)

The total pressure of a mixture of non-reacting gases X(0.6 g) and Y(0.45 g) in a vessel is 740 mm of Hg. The partial pressure of the gas X is mm of Hg. (Nearest Integer)
(Given: molar mass X = 20 and Y = 45 g mol$$^{-1}$$)

At 27°C, a solution containing 2.5 g of solute in 250.0 mL of solution exerts an osmotic pressure of 400 Pa. The molar mass of the solute is g mol$$^{-1}$$ (Nearest integer)
(Given: R = 0.083 L bar$$^{-1}$$ mol$$^{-1}$$)

The logarithm of equilibrium constant for the reaction $$Pd^{2+} + 4Cl^- \rightleftharpoons PdCl_4^{2-}$$ is (Nearest integer)
Given: $$\dfrac{2.303RT}{F} = 0.06$$ V
$$Pd^{2+}_{(aq)} + 2e^- \rightleftharpoons Pd(s)$$ $$E^o = 0.83$$ V
$$PdCl_4^{2-}(aq) + 2e^- \rightleftharpoons Pd(s) + 4Cl^-(aq)$$ $$
$$E^o = 0.65$$ V

$$A \rightarrow B$$
The rate constants of the above reaction at 200 K and 300 K are 0.03 min$$^{-1}$$ and 0.05 min$$^{-1}$$ respectively. The activation energy for the reaction is J (Nearest integer)
(Given: ln 10 = 2.3, R = 8.3 J K$$^{-1}$$ mol$$^{-1}$$, log 5 = 0.70, log 3 = 0.48, log 2 = 0.30)

The oxidation state of phosphorus in hypophosphoric acid is

How many of the transformation given below would result in aromatic amines?