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NTA JEE Main 30th January 2023 Shift 1 - Chemistry

For the following questions answer them individually

Match List - I with List - II

LIST-I (Atomic number)LIST-II (Block of periodic table)
(A) 37I. p-block
(B) 78II. d-block
(C) 52III. f-block
(D) 65IV. s-block

Choose the correct answer from the options given below:

For OF$$_2$$ molecule consider the following:
(A) Number of lone pairs on oxygen is 2.
(B) FOF angle is less than 104.5°.
(C) Oxidation state of O is -2.
(D) Molecule is bent 'V' shaped.
(E) Molecular geometry is linear.
Correct options are:

Match List I with List II

List I (molecules/ions)List II (No. of lone pairs of e$$^-$$ on central atom)
(A) IF$$_7$$I. Three
(B) ICl$$_4^-$$II. One
(C) XeF$$_6$$III. Two
(D) XeF$$_2$$IV. Zero

Choose the correct answer from the options given below:

Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R).
Assertion (A): In expensive scientific instruments, silica gel is kept in watch-glasses or in semipermeable membrane bags.
Reason (R): Silica gel adsorbs moisture from air via adsorption, thus protects the instrument from water corrosion (rusting) and / or prevents malfunctioning.
In the light of the above statements, choose the correct answer from the options given below:

What is the correct order of acidity of the protons marked $$A - D$$ in the given compounds?

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Formation of photochemical smog involves the following reaction in which A, B and C are respectively.
(i) NO$$_2$$ $$\xrightarrow{h\nu}$$ A + B
(ii) B + O$$_2$$ $$\to$$ C
(iii) A + C $$\to$$ NO$$_2$$ + O$$_2$$
Choose the correct answer from the options below:

In the extraction of copper, its sulphide ore is heated in a reverberatory furnace after mixing with silica to:

Which of the following is correct order of ligand field strength?

To inhibit the growth of tumours, identify the compounds used from the following:
(A) EDTA
(B) Coordination Compounds of Pt
(C) D-Penicillamine
(D) Cis - Platin
Choose the correct answer from the option given below:

Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R).
Assertion (A): Ketoses give Seliwanoff's test faster than Aldoses.
Reason (R): Ketoses undergo $$\beta$$-elimination followed by formation of furfural.
In the light of the above statements, choose the correct answer from the options given below:

The energy of one mole of photons of radiation of frequency $$2 \times 10^{12}$$ Hz in J mol$$^{-1}$$ is ______ . (Nearest integer)
(Given: h $$= 6.626 \times 10^{-34}$$ Js, N$$_A = 6.022 \times 10^{23}$$ mol$$^{-1}$$)

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600 mL of 0.01 M HCl is mixed with 400 mL of 0.01 M H$$_2$$SO$$_4$$. The pH of the mixture is ______ $$\times 10^{-2}$$. (Nearest integer)
[Given log2 = 0.30, log3 = 0.48, log5 = 0.69, log7 = 0.84, log11 = 1.04]

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A 300 mL bottle of soft drink has 0.2M CO$$_2$$ dissolved in it. Assuming CO$$_2$$ behaves as an ideal gas, the volume of the dissolved CO$$_2$$ at STP is ______ mL. (Nearest integer)
Given: At STP, molar volume of an ideal gas is 22.7 L mol$$^{-1}$$

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A solution containing 2 g of a non-volatile solute in 20 g of water boils at 373.52 K. The molecular mass of the solute is ______ g mol$$^{-1}$$. (Nearest integer)
Given, water boils at 373 K, K$$_b$$ for water $$= 0.52$$ K kg mol$$^{-1}$$

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Some amount of dichloromethane CH$$_2$$Cl$$_2$$ is added to 671.141 mL of chloroform CHCl$$_3$$ to prepare $$2.6 \times 10^{-3}$$ M solution of CH$$_2$$Cl$$_2$$ DCM. The concentration of DCM is ______ ppm (by mass).
Given: Atomic mass: C = 12; H: 1; Cl = 35.5 density of CHCl$$_3$$ = 1.49 g cm$$^{-3}$$

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Consider the cell
Pt, H$$_2$$(g, 1 atm) | H$$^+$$ aq, 1M | Fe$$^{3+}$$ aq, Fe$$^{2+}$$ aq | Pt s
When the potential of the cell is 0.712 V at 298 K, the ratio Fe$$^{2+}$$/Fe$$^{3+}$$ is ______ (Nearest integer)
Given: Fe$$^{3+}$$ + e$$^-$$ = Fe$$^{2+}$$, E° Fe$$^{3+}$$, Fe$$^{2+}$$ Pt = 0.771, $$\frac{2.303RT}{F} = 0.06$$ V

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If compound A reacts with B following first order kinetics with rate constant $$2.011 \times 10^{-3}$$ s$$^{-1}$$. The time taken by A (in seconds) to reduce from $$7$$ g to $$2$$ g will be ______. (Nearest Integer)
log5 = 0.698, log7 = 0.845, log2 = 0.301

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A trisubstituted compound 'A', C$$_{10}$$H$$_{12}$$O$$_2$$ gives neutral FeCl$$_3$$ test positive. Treatment of compound 'A' with NaOH and CH$$_3$$Br gives C$$_{11}$$H$$_{14}$$O$$_2$$, with hydroiodic acid gives methyl iodide and with hot conc. NaOH gives a compound B, C$$_{10}$$H$$_{12}$$O$$_2$$. Compound 'A' also decolourises alkaline KMnO$$_4$$. The number of $$\pi$$ bond/s present in the compound 'A' is ______.

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