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NTA JEE Main 29th January 2023 Shift 1 - Chemistry

For the following questions answer them individually

For 1 mol of gas, the plot of pV vs p is shown below. p is the pressure and V is the volume of the gas.

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What is the value of compressibility factor at point A?

The magnetic behaviour of Li$$_2$$O, Na$$_2$$O$$_2$$ and KO$$_2$$, respectively, are

The correct order of hydration enthalpies is
(A) K$$^+$$
(B) Rb$$^+$$
(C) Mg$$^{2+}$$
(D) Cs$$^+$$
(E) Ca$$^{2+}$$
Choose the correct answer from the options below:

Correct statement about smog is

The standard electrode potential (M$$^{3+}$$/M$$^{2+}$$) for V, Cr, Mn & Co are $$-0.26$$ V, $$-0.41$$ V, $$+1.57$$ V and $$+1.97$$ V, respectively. The metal ions which can liberate H$$_2$$ from a dilute acid are

Following figure shows dependence of molar conductance of two electrolytes on concentration. $$\Lambda^0_m$$ is the limiting molar conductivity.

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The number of Incorrect statement(s) from the following is ______
(A) $$\Lambda^0_m$$ for electrolyte A is obtained by extrapolation
(B) For electrolyte B, $$\Lambda_m$$ Vs $$\sqrt{c}$$ graph is a straight line with intercept equal to $$\Lambda^0_m$$
(C) At infinite dilution, the value of degree of dissociation approach zero for electrolyte B.
(D) $$\Lambda_m$$ for any electrolyte A or B can be calculated using $$\lambda°$$ for individual ions.

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Which of the following salt solutions would coagulate the colloid solution formed when FeCl$$_3$$ is added to NaOH solution, at the fastest rate?

The reaction representing the Mond process for metal refining is ______

"A" obtained by Ostwald's method involving air oxidation of NH$$_3$$, upon further air oxidation produces "B". "B" on hydration forms an oxoacid of Nitrogen along with evolution of "A". The oxoacid also produces "A" and gives positive brown ring test

Chiral complex from the following is:
Here en = ethylene diamine

The increasing order of pK$$_a$$ for the following phenols is
(A) 2,4-Dinitrophenol
(B) 4-Nitrophenol
(C) 2,4,5-Trimethylphenol
(D) Phenol
(E) 3-Chlorophenol
Choose the correct answer from the option given below:

Match List I with List II.

List I (Reaction)List II (Reagents)
(A) Hoffmann Degradation(I) Conc. KOH, $$\Delta$$
(B) Clemmensen reduction(II) CHCl$$_3$$, NaOH/H$$_3$$O$$^+$$
(C) Cannizzaro reaction(III) Br$$_2$$, NaOH
(D) Reimer-Tiemann reaction(IV) Zn $$-$$ Hg/HCl

Match List I with List II

List I (Antimicrobials)List II (Names)
(A) Narrow Spectrum Antibiotic(I) Furacin
(B) Antiseptic(II) Sulphur dioxide
(C) Disinfectants(III) Penicillin-G
(D) Broad spectrum antibiotic(IV) Chloramphenicol

Consider the following reaction approaching equilibrium at $$27°$$C and 1 atm pressure
$$\text{A} + \text{B} \underset{K_r=10^2}{\overset{K_f=10^3}{\rightleftharpoons}} \text{C} + \text{D}$$
The standard Gibb's energy change $$(\Delta_r G°)$$ at $$27°$$C is $$(-)$$ ______ kJ mol$$^{-1}$$. (Nearest integer).
(Given: R $$= 8.3$$ J K$$^{-1}$$ mol$$^{-1}$$ and $$\ln 10 = 2.3$$)

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Water decomposes at 2300 K
$$\text{H}_2\text{O}(g) \to \text{H}_2(g) + \frac{1}{2}\text{O}_2(g)$$
The percent of water decomposing at 2300 K and 1 bar is ______ (Nearest integer). Equilibrium constant for the reaction is $$2 \times 10^{-3}$$ at 2300 K

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17 mg of a hydrocarbon (M.F. C$$_{10}$$H$$_{16}$$) takes up 8.40 mL of the H$$_2$$ gas measured at 0°C and 760 mm of Hg. Ozonolysis of the same hydrocarbon yields

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The number of double bond/s present in the hydrocarbon is

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Solid Lead nitrate is dissolved in 1 litre of water. The solution was found to boil at $$100.15°$$C. When $$0.2$$ mol of NaCl is added to the resulting solution, it was observed that the solution froze at $$-0.8°$$C. The solutibility product of PbCl$$_2$$ formed is ______ $$\times 10^{-6}$$ at 298 K. (Nearest integer)
Given: K$$_b = 0.5$$ K kg mol$$^{-1}$$ and K$$_f = 1.8$$ kg mol$$^{-1}$$. Assume molality to be equal to molarity in all cases.

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For certain chemical reaction X $$\to$$ Y, the rate of formation of product is plotted against the time as shown in the figure. The number of Correct statement/s from the following is ______

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(A) Over all order of this reaction is one
(B) Order of this reaction can't be determined
(C) In region-I and III, the reaction is of first and zero order respectively
(D) In region-II, the reaction is of first order
(E) In region-II, the order of reaction is in the range of 0.1 to 0.9.

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