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NTA JEE Main 28th June 2022 Shift 1 - Chemistry

For the following questions answer them individually

The incorrect statement about the imperfections in solids is

Given are two statements one is labelled as Assertion and other is labelled as Reason.
Assertion: Magnesium can reduce $$Al_2O_3$$ at a temperature below $$1350°$$C, while above $$1350°$$C aluminium can reduce MgO.
Reason: The melting and boiling points of magnesium are lower than those of aluminium.

Given below are two statements :
Statement I: The pentavalent oxide of group-15 element, $$E_2O_5$$, is less acidic than trivalent oxide, $$E_2O_3$$, of the same element.
Statement II : The acidic character of trivalent oxide of group 15 elements, $$E_2O_3$$, decreases down the group.

Given below are two statements :
Statement I: $$[Ni(CN)_4]^{2-}$$ is square planar and diamagnetic complex, with $$dsp^2$$ hybridization for Ni but $$[Ni(CO)_4]$$ is tetrahedral, paramagnetic and with $$sp^3$$ hybridication for Ni.
Statement II : $$[NiCl_4]^{2-}$$ and $$[Ni(CO)_4]$$ both have same d-electron configuration, have same geometry and are paramagnetic.
In light the above statements, choose the correct answer form the options given below

If the work function of a metal is $$6.63 \times 10^{-19}$$ J, the maximum wavelength of the photon required to remove a photoelectron from the metal is ______ nm. Nearest integer
[Given : $$h = 6.63 \times 10^{-34}$$ J s, and $$c = 3 \times 10^{8}$$ m s$$^{-1}$$]

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A $$2.0$$ g sample containing $$MnO_2$$ is treated with HCl liberating $$Cl_2$$. The $$Cl_2$$ gas is passed into a solution of KI and $$60.0$$ mL of $$0.1$$ M $$Na_2S_2O_3$$ is required to titrate the liberated iodine. The percentage of $$MnO_2$$ in the sample is ______ Nearest integer
[Atomic masses (in u) Mn = 55; Cl = 35.5; O = 16, I = 127, Na = 23, K = 39, S = 32]

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The vapour pressures of two volatile liquids A and B at $$25°$$C are $$50$$ Torr and $$100$$ Torr, respectively. If the liquid mixture contains $$0.3$$ mole fraction of A, then the mole fraction of liquid B in the vapour phase is $$\frac{x}{17}$$. The value of $$x$$ is ______

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For a first order reaction A $$\to$$ B, the rate constant, $$k = 5.5 \times 10^{-14}$$ s$$^{-1}$$. The time required for $$67\%$$ completion of reaction is $$x \times 10^{-1}$$ times the half life of reaction. The value of $$x$$ is ______ Nearest integer) (Given : $$\log 3 = 0.4771$$)

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