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NTA JEE Main 27th June 2022 Shift 2 - Chemistry

For the following questions answer them individually

Identify the incorrect statement for $$PCl_5$$ from the following.

Statement I: Leaching of gold with cyanide ion in absence of air/$$O_2$$ leads to cyano complex of Au(III).
Statement II: Zinc is oxidized during the displacement reaction carried out for gold extraction.
In the light of the above statements, choose the correct answer from the options given below

Given below are two statements: one is labelled as Assertion and the other is labelled as Reason.
Assertion: Flourine forms one oxoacid.
Reason: Flourine has smallest size amongst all halogens and is highly electronegative.
In the light of the above statements, choose the most appropriate answer from the Question: options given
below.

On the surface of polar stratospheric clouds, hydrolysis of chlorine nitrate gives A and B while its reaction with HCl produces B and C. A, B and C are, respectively

Arrange the following coordination compounds in the increasing order of magnetic moments. (Atomic numbers: Mn = 25; Fe = 26)
A. $$[FeF_6]^{3-}$$
B. $$[Fe(CN)_6]^{3-}$$
C. $$[MnCl_6]^{3-}$$ (high spin)
D. $$[Mn(CN)_6]^{3-}$$
Choose the correct answer from the options given below

Match List-I with List-II
                    List - I                                                            List - II

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Decarboxylation of all six possible forms of diaminobenzoic acids $$C_6H_3(NH_2)_2COOH$$ yields three products A, B and C. Three acids give a product 'A', two acids give a product 'B' and one acid give a product 'C'. The melting point of product 'C' is

Match List - I with List - II.
         List - I                              List - II

(A) Antipyretic(I) Reduces pain
(B) Analgesic(II) Reduces stress
(C) Tranquilizer(III) Reduces fever
(D) Antacid(IV) Reduces acidity(stomach)

Choose the correct answer from the options given below

Match List - I with List - II.

List-I (Anion)List-II (gas evolved on reaction with dil. $$H_2SO_4$$)
(A) $$CO_3^{2-}$$(I) Colourless gas which turns lead acetate paper black.
(B) $$S^{2-}$$(II) Colourless gas which turns acidified potassium dichromate solution green.
(C) $$SO_3^{2-}$$(III) Brown fumes which turns acidified KI solution containing starch blue.
(D) $$NO_2^-$$(IV) Colourless gas evolved with brisk effervescence, which turns lime water milky.

Choose the correct answer from the options given below

Given below are two statements.
Statement I: Maltose has two $$\alpha - D$$ - glucose units linked at $$C_1$$ and $$C_4$$ and is a reducing sugar.
Statement II: Maltose has two monosaccharides: $$\alpha$$-D-glucose and $$\beta$$-D-glucose linked at $$C_1$$ and $$C_6$$ and it is a non-reducing sugar.
In the light of the above statements, choose the correct answer from the options Question: given below.

$$116$$ g of a substance upon dissociation reaction, yields $$7.5$$ g of hydrogen, $$60$$ g of oxygen and $$48.5$$ g of carbon. Given that the atomic masses of H, O and C are 1, 16 and 12, respectively. The data agrees with how many formulae of the following?
A. $$CH_3COOH$$
B. HCHO
C. $$CH_3OOCH_3$$
D. $$CH_3CHO$$

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When 5 moles of He gas expand isothermally and reversibly at $$300$$ K from $$10$$ litre to $$20$$ litre, the magnitude of the maximum work obtained is ______ J. [nearest integer] (Given : $$R = 8.3$$ J K$$^{-1}$$ mol$$^{-1}$$ and $$\log 2 = 0.3010$$)

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$$0.25$$ g of an organic compound containing chlorine gave $$0.40$$ g of silver chloride in Carius estimation. The percentage of chlorine present in the compound is ______ [in nearest integer]
(Given: Molar mass of Ag is $$108$$ g mol$$^{-1}$$ and that of Cl is $$35.5$$ g mol$$^{-1}$$)

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A solution containing $$2.5 \times 10^{-3}$$ kg of a solute dissolved in $$75 \times 10^{-3}$$ kg of water boils at $$373.535$$ K. The molar mass of the solute is ______ mol$$^{-1}$$. [nearest integer] (Given : $$K_b(H_2O) = 0.52$$ K kg mol$$^{-1}$$ and boiling point of water $$= 373.15$$ K)

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It has been found that for a chemical reaction with rise in temperature by $$9$$ K the rate constant gets doubled. Assuming a reaction to be occurring at $$300$$ K, the value of activation energy is found to be ______ kJ mol$$^{-1}$$. [nearest integer] (Given $$\ln 10 = 2.3, R = 8.3$$ J K$$^{-1}$$ mol$$^{-1}$$, $$\log 2 = 0.30$$)

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