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NTA JEE Main 27th June 2022 Shift 1 - Chemistry

For the following questions answer them individually

Given below are two statements : one is labelled as Assertion and the other is labelled as Reason.
Assertion: The ionic radii of $$O^{2-}$$ and $$Mg^{2+}$$ are same.
Reason: Both $$O^{2-}$$ and $$Mg^{2+}$$ are isoelectronic species.

Based upon VSEPR theory, match the shape (geometry) of the molecules in List-I with the molecules in List-II

List-I (Shape)List-II (Molecules)
A T-shapedI. $$XeF_4$$
B Trigonal planarII. $$SF_4$$
C Square planarIII. $$ClF_3$$
D See-sawIV. $$BF_3$$

Match List - I with List - II.

List-IList-II
(A) Spontaneous process(I) $$\Delta H < 0$$
(B) Process with $$\Delta P = 0, \Delta T = 0$$(II) $$\Delta G_{T,P} < 0$$
(C) $$\Delta H_{reaction}$$(III) Isothermal and isobaric process
(D) Exothermic Process(IV) [Bond energies in reactants] - [Bond energies in products]

Choose the correct answer from the options given below

Match List - I with List - II.

List-I (Si-Compounds)List-II (Si-Polymeric/Other Products)
A $$(CH_3)_4Si$$I Chain Silicone
B $$(CH_3)Si(OH)_3$$II Dimeric Silicone
C $$(CH_3)_2Si(OH)_2$$III Silane
D $$(CH_3)_3Si(OH)$$IV 2D-Silicone

Choose the correct answer from the options given below

L-isomer of a compound 'A'($$C_4H_8O_4$$) gives a positive test with $$[Ag(NH_3)_2]^+$$. Treatment of 'A' with acetic anhydride yields triacetate derivative. Compound 'A' produces an optically active compound (B) and an optically inactive compound (C) on treatment with bromine water and $$HNO_3$$ respectively. Compound (A) is :

Given below are two Statements :
Statement I : Classical smog occurs in cool humid climate. It is a reducing mixture of smoke, fog and sulphur dioxide.
Statement II : Photochemical smog has components, ozone, nitric oxide, acrolein, formaldehyde, PAN etc.
In the light of the above statements, choose the most appropriate answer from the options given below.

Given below are two statements : one is labelled as Assertion and the other is labelled as Reason.
Assertion: At $$10°$$C, the density of a $$5$$ M solution of KCl [atomic masses of K & Cl are $$39$$ & $$35.5$$ g mol$$^{-1}$$ respectively], is 'x' g mL$$^{-1}$$. The solution is cooled to $$-21°$$C. The molality of the solution will remain unchanged.
Reason: The molality of a solution does not change with temperature as mass remains unaffected with temperature.
In the light of the above statements, choose the most appropriate answer from the options given below.

Match List - I with List - II.

List-IList-II
A Lyophilic colloidI Liquid-liquid colloid
B EmulsionII Protective colloid
C Positively charged colloidIII $$FeCl_3 + NaOH$$
D Negatively charged colloidIV $$FeCl_3$$ + hot water

Choose the correct answer from the options given below

Match List - I with List - II.

List-IList-II
A Concentration of gold oreI Aniline
B Leaching of aluminaII NaOH
C Froth stabiliserIII $$SO_2$$
D Blister copperIV NaCN

Choose the correct answer from the options given below

'A' and 'B' respectively are
A $$\xrightarrow[(2) Zn-H_2O]{(1) O_3 \atop}$$ Ethane-1,2-dicarbaldehyde + Glyoxal/Oxaldehyde
B $$\xrightarrow[(2) Zn-H_2O]{(1) O_3 \atop}$$ 5-oxohexanal

Given below are two statements :
Statement - I : In Hofmann degradation reaction, the migration of only an alkyl group takes place from carbonyl carbon of the amide to the nitrogen atom.
Statement - II : The group is migrated in Hofmann degradation reaction to electron deficient atom.
In the light of the above statements, choose the most appropriate answer from the options given below

Match List - I with List - II.

List-I (Polymer)List-II (Used in)
A BakeliteI Radio and television cabinets
B GlyptalII Electrical switches
C PVCIII Paints and Lacquers
D PolystyreneIV Water pipes

$$2NOCl(g) \rightleftharpoons 2NO(g) + Cl_2(g)$$
In an experiment, $$2.0$$ moles of NOCl was placed in a one-litre flask and the concentration of NO after equilibrium established, was found to be $$0.4$$ mol/L. The equilibrium constant at $$30°$$C is ______ $$\times 10^{-4}$$.

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Metal deficiency defect is shown by $$Fe_{0.93}O$$. In the crystal, some $$Fe^{2+}$$ cations are missing and loss of positive charge is compensated by the presence of $$Fe^{3+}$$ ions. The percentage of $$Fe^{2+}$$ ions in the $$Fe_{0.93}O$$ crystals is ______ (Nearest integer)

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$$2$$ g of a non-volatile non-electrolyte solute is dissolved in $$200$$ g of two different solvents A and B whose ebullioscopic constants are in the ratio of $$1 : 8$$. The elevation in boiling points of A and B are in the ratio $$\frac{x}{y}$$ ($$x : y$$). The value of $$y$$ is ______ (Nearest Integer)

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The limiting molar conductivities of NaI, $$NaNO_3$$ and $$AgNO_3$$ are $$12.7, 12.0$$ and $$13.3$$ mS m$$^2$$ mol$$^{-1}$$, respectively (all at $$25°$$C). The limiting molar conductivity of AgI at this temperature is ______ mS m$$^2$$ mol$$^{-1}$$.

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The rate constant for a first order reaction is given by the following equation :
$$\ln k = 33.24 - \frac{2.0 \times 10^4 K}{T}$$
The Activation energy for the reaction is given by ______ kJ mol$$^{-1}$$. (In Nearest integer) (Given : $$R = 8.3$$ J K$$^{-1}$$ mol$$^{-1}$$)

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