NTA JEE Main 22nd July 2021 Shift 1 - Chemistry

Instructions

For the following questions answer them individually

NTA JEE Main 22nd July 2021 Shift 1 - Chemistry - Question 31


Which one of the following statements for D.I. Mendeleeff, is incorrect?

NTA JEE Main 22nd July 2021 Shift 1 - Chemistry - Question 32


Match List-I with List-II

(a) SF$$_4$$ (i) sp$$^3$$d$$^2$$
(b) IF$$_5$$ (ii) d$$^2$$sp$$^3$$
(c) NO$$_2^+$$ (iii) sp$$^3$$d
(d) NH$$_4^+$$ (iv) sp$$^3$$
 (v) sp

Choose the correct answer from the options given below:

NTA JEE Main 22nd July 2021 Shift 1 - Chemistry - Question 33


Match List-I with List-II

(a) Ba(i) Organic solvent soluble compounds
(b) Ca(ii) Outer electronic configuration 6s$$^2$$
(c) Li(iii) Oxalate insoluble in water
(d) Na(iv) Formation of very strong monoacidic base

Choose the correct answer from the options given below:

NTA JEE Main 22nd July 2021 Shift 1 - Chemistry - Question 34


Given below are the statements about diborane
(a) Diborane is prepared by the oxidation of NaBH$$_4$$ with I$$_2$$
(b) Each boron atom is in sp$$^2$$ hybridized state
(c) Diborane has one bridged 3 centre-2-electron bond
(d) Diborane is a planar molecule
The option with correct statement(s) is

NTA JEE Main 22nd July 2021 Shift 1 - Chemistry - Question 35


Which purification technique is used for high boiling organic liquid compound (decomposes near its boiling point)?

NTA JEE Main 22nd July 2021 Shift 1 - Chemistry - Question 36


Which of the following compounds does not exhibit resonance?

NTA JEE Main 22nd July 2021 Shift 1 - Chemistry - Question 37


Which of the following molecules does not show stereo isomerism?

NTA JEE Main 22nd July 2021 Shift 1 - Chemistry - Question 38



In the chemical reactions given above A and B respectively are:

NTA JEE Main 22nd July 2021 Shift 1 - Chemistry - Question 39


The water having more dissolved O$$_2$$ is:

NTA JEE Main 22nd July 2021 Shift 1 - Chemistry - Question 40


Which one of the following 0.06 M aqueous solutions has lowest freezing point?

NTA JEE Main 22nd July 2021 Shift 1 - Chemistry - Question 41


Isotope(s) of hydrogen which emits low energy $$\beta^-$$ particles with $$t_{1/2}$$ value > 12 years is/are

NTA JEE Main 22nd July 2021 Shift 1 - Chemistry - Question 42


When silver nitrate solution is added to potassium iodide solution then the sol produced is:

NTA JEE Main 22nd July 2021 Shift 1 - Chemistry - Question 43


Sulphide ion is soft base and its ores are common for metals
(a) Pb (b) Al (c) Ag (d) Mg
Choose the correct answer from the options given below

NTA JEE Main 22nd July 2021 Shift 1 - Chemistry - Question 44


Which one of the following group-15 hydride is the strongest reducing agent?

NTA JEE Main 22nd July 2021 Shift 1 - Chemistry - Question 45


The set having ions which are coloured and paramagnetic both is -

NTA JEE Main 22nd July 2021 Shift 1 - Chemistry - Question 46


Which of the following compounds will provide a tertiary alcohol on reaction with excess of CH$$_3$$MgBr followed by hydrolysis?

NTA JEE Main 22nd July 2021 Shift 1 - Chemistry - Question 47


An organic compound A (C$$_6$$H$$_6$$O) gives dark green colouration with ferric chloride. On treatment with CHCl$$_3$$ and KOH, followed by acidification gives compound B. Compound B can also be obtained from compound C on reaction with pyridinium chlorochromate (PCC). Identify A, B and C.

NTA JEE Main 22nd July 2021 Shift 1 - Chemistry - Question 48


Which one of the following reactions does not occur?

NTA JEE Main 22nd July 2021 Shift 1 - Chemistry - Question 49


Match List-I with List-II :

(a) Chloroprene(i)  page9_img1
(b) Neoprene(ii) page9_img2
(c) Acrylonitrile(iii) page9_img3
(d) Isoprene(iv) CH$$_2$$=CH-CN

Choose the correct answer from the options given

NTA JEE Main 22nd July 2021 Shift 1 - Chemistry - Question 50


Thiamine and pyridoxine are also known respectively as:

NTA JEE Main 22nd July 2021 Shift 1 - Chemistry - Question 51


Methylation of 10 g of benzene gave 9.2 g of toluene. Calculate the percentage yield of toluene (Nearest integer)

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NTA JEE Main 22nd July 2021 Shift 1 - Chemistry - Question 52


Number of electrons that Vanadium (Z = 23) has in p-orbitals is equal to:

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NTA JEE Main 22nd July 2021 Shift 1 - Chemistry - Question 53


If the standard molar enthalpy change for combustion of graphite powder is $$-2.48 \times 10^2$$ kJ mol$$^{-1}$$, the amount of heat generated on combustion of 1 g of graphite powder in kJ (Nearest integer):

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NTA JEE Main 22nd July 2021 Shift 1 - Chemistry - Question 54


Value of K$$_P$$ for the equilibrium reaction N$$_2$$O$$_4$$(g) $$\rightleftharpoons$$ 2NO$$_2$$(g) at 288 K is 47.9. The K$$_C$$ for this reaction at same temperature is (Nearest integer)
(R = 0.083 L bar K$$^{-1}$$ mol$$^{-1}$$)

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NTA JEE Main 22nd July 2021 Shift 1 - Chemistry - Question 55


The number of acyclic structural isomers (including geometrical isomers) for pentene are ___.

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NTA JEE Main 22nd July 2021 Shift 1 - Chemistry - Question 56


A copper complex crystallising in a CCP lattice with a cell edge of 0.4518 nm has been revealed by employing X-ray diffraction studies. The density of a copper complex is found to be 7.62 g cm$$^{-3}$$. The molar mass of copper complex is ___ gmol$$^{-1}$$
(Nearest integer): [Given : N$$_A$$ = 6.022 $$\times 10^{23}$$ mol$$^{-1}$$]

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NTA JEE Main 22nd July 2021 Shift 1 - Chemistry - Question 57


If the concentration of glucose (C$$_6$$H$$_{12}$$O$$_6$$) in blood is 0.72 gL$$^{-1}$$, the molarity of glucose in blood is ___ $$\times 10^{-3}$$M (Nearest integer):
[Given : Atomic mass of C = 12, H = 1, O = 16 u]

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NTA JEE Main 22nd July 2021 Shift 1 - Chemistry - Question 58


Assume a cell with the following reaction Cu$$_{(s)}$$ + 2Ag$$^+$$(1 $$\times 10^{-3}$$M) $$\to$$ Cu$$^{2+}$$(0.250M) + 2Ag$$_{(s)}$$
E$$^\circ_{cell}$$ = 2.97 V
E$$_{cell}$$ for the above reaction is ___ V.
(Nearest integer)
[Given : log 2.5 = 0.3979, T = 298 K]

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NTA JEE Main 22nd July 2021 Shift 1 - Chemistry - Question 59


N$$_2$$O$$_{5(g)} \to$$ 2NO$$_{2(g)}$$ + $$\frac{1}{2}$$O$$_{2(g)}$$
In the above first order reaction the initial concentration of N$$_2$$O$$_5$$ is $$2.40 \times 10^{-2}$$ mol L$$^{-1}$$ at 318 K. The concentration of N$$_2$$O$$_5$$ after 1 hour was $$1.60 \times 10^{-2}$$ mol L$$^{-1}$$. The rate constant of the reaction at 318 K is ___ $$\times 10^{-3}$$ min$$^{-1}$$ (Nearest integer):
[Given : log 3 = 0.477, log 5 = 0.699]

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NTA JEE Main 22nd July 2021 Shift 1 - Chemistry - Question 60


The total number of unpaired electrons present in [Co(NH$$_3$$)$$_6$$]Cl$$_2$$ and [Co(NH$$_3$$)$$_6$$]Cl$$_3$$ is ___.

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