For the following questions answer them individually
Which one of the following statements for D.I. Mendeleeff, is incorrect?
Match List-I with List-II
| (a) SF$$_4$$ | Â (i) sp$$^3$$d$$^2$$ |
| (b) IF$$_5$$ | Â (ii) d$$^2$$sp$$^3$$ |
| (c) NO$$_2^+$$ | Â (iii) sp$$^3$$d |
| (d) NH$$_4^+$$ | Â (iv) sp$$^3$$ |
| Â (v) sp |
Choose the correct answer from the options given below:
Match List-I with List-II
| (a) Ba | (i) Organic solvent soluble compounds |
| (b) Ca | (ii) Outer electronic configuration 6s$$^2$$ |
| (c) Li | (iii) Oxalate insoluble in water |
| (d) Na | (iv) Formation of very strong monoacidic base |
Choose the correct answer from the options given below:
Given below are the statements about diborane
(a) Diborane is prepared by the oxidation of NaBH$$_4$$ with I$$_2$$
(b) Each boron atom is in sp$$^2$$ hybridized state
(c) Diborane has one bridged 3 centre-2-electron bond
(d) Diborane is a planar molecule
The option with correct statement(s) is
Which purification technique is used for high boiling organic liquid compound (decomposes near its boiling point)?
Which of the following compounds does not exhibit resonance?
Which of the following molecules does not show stereo isomerism?
In the chemical reactions given above A and B respectively are:
The water having more dissolved O$$_2$$ is:
Which one of the following 0.06 M aqueous solutions has lowest freezing point?
Isotope(s) of hydrogen which emits low energy $$\beta^-$$ particles with $$t_{1/2}$$ value > 12 years is/are
When silver nitrate solution is added to potassium iodide solution then the sol produced is:
Sulphide ion is soft base and its ores are common for metals
(a) Pb (b) Al (c) Ag (d) Mg
Choose the correct answer from the options given below
Which one of the following group-15 hydride is the strongest reducing agent?
The set having ions which are coloured and paramagnetic both is -
Which of the following compounds will provide a tertiary alcohol on reaction with excess of CH$$_3$$MgBr followed by hydrolysis?
An organic compound A (C$$_6$$H$$_6$$O) gives dark green colouration with ferric chloride. On treatment with CHCl$$_3$$ and KOH, followed by acidification gives compound B. Compound B can also be obtained from compound C on reaction with pyridinium chlorochromate (PCC). Identify A, B and C.
Which one of the following reactions does not occur?
Match List-I with List-II :
| (a) Chloroprene | (i)Â
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| (b) Neoprene | (ii)
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| (c) Acrylonitrile | (iii)
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| (d) Isoprene | (iv) CH$$_2$$=CH-CN |
Choose the correct answer from the options given
Thiamine and pyridoxine are also known respectively as:
Methylation of 10 g of benzene gave 9.2 g of toluene. Calculate the percentage yield of toluene (Nearest integer)
Number of electrons that Vanadium (Z = 23) has in p-orbitals is equal to:
If the standard molar enthalpy change for combustion of graphite powder is $$-2.48 \times 10^2$$ kJ mol$$^{-1}$$, the amount of heat generated on combustion of 1 g of graphite powder in kJ (Nearest integer):
Value of K$$_P$$ for the equilibrium reaction N$$_2$$O$$_4$$(g) $$\rightleftharpoons$$ 2NO$$_2$$(g) at 288 K is 47.9. The K$$_C$$ for this reaction at same temperature is (Nearest integer)
(R = 0.083 L bar K$$^{-1}$$ mol$$^{-1}$$)
The number of acyclic structural isomers (including geometrical isomers) for pentene are ___.
A copper complex crystallising in a CCP lattice with a cell edge of 0.4518 nm has been revealed by employing X-ray diffraction studies. The density of a copper complex is found to be 7.62 g cm$$^{-3}$$. The molar mass of copper complex is ___ gmol$$^{-1}$$
(Nearest integer): [Given : N$$_A$$ = 6.022 $$\times 10^{23}$$ mol$$^{-1}$$]
If the concentration of glucose (C$$_6$$H$$_{12}$$O$$_6$$) in blood is 0.72 gL$$^{-1}$$, the molarity of glucose in blood is ___ $$\times 10^{-3}$$M (Nearest integer):
[Given : Atomic mass of C = 12, H = 1, O = 16 u]
Assume a cell with the following reaction Cu$$_{(s)}$$ + 2Ag$$^+$$(1 $$\times 10^{-3}$$M) $$\to$$ Cu$$^{2+}$$(0.250M) + 2Ag$$_{(s)}$$
E$$^\circ_{cell}$$ = 2.97 V
E$$_{cell}$$ for the above reaction is ___ V.
(Nearest integer)
[Given : log 2.5 = 0.3979, T = 298 K]
N$$_2$$O$$_{5(g)} \to$$ 2NO$$_{2(g)}$$ + $$\frac{1}{2}$$O$$_{2(g)}$$
In the above first order reaction the initial concentration of N$$_2$$O$$_5$$ is $$2.40 \times 10^{-2}$$ mol L$$^{-1}$$ at 318 K. The concentration of N$$_2$$O$$_5$$ after 1 hour was $$1.60 \times 10^{-2}$$ mol L$$^{-1}$$. The rate constant of the reaction at 318 K is ___ $$\times 10^{-3}$$ min$$^{-1}$$ (Nearest integer):
[Given : log 3 = 0.477, log 5 = 0.699]
The total number of unpaired electrons present in [Co(NH$$_3$$)$$_6$$]Cl$$_2$$ and [Co(NH$$_3$$)$$_6$$]Cl$$_3$$ is ___.