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NTA JEE Main 2nd September 2020 Shift 2 - Chemistry

For the following questions answer them individually

Match the type of interaction in column A with the distance dependence of their interaction energy in column B:
A                                               B
(i) ion - ion                        (a) $$\frac{1}{r}$$
(ii) Dipole - dipole         (b) $$\frac{1}{r^2}$$
(iii) London dispersion  (c) $$\frac{1}{r^3}$$
                                          (iv) $$\frac{1}{r^6}$$

The results given in the below table were obtained during kinetic studies of the following reaction:
$$2A + B \to C + D$$

Experiment[A]/mol L$$^{-1}$$[B]/mol L$$^{-1}$$Initial rate/mol L$$^{-1}$$ min$$^{-1}$$
I0.10.1$$6.00 \times 10^{-3}$$
II0.10.2$$2.40 \times 10^{-2}$$
III0.20.1$$1.20 \times 10^{-2}$$
IVX0.2$$7.20 \times 10^{-2}$$
V0.3Y$$2.88 \times 10^{-1}$$


X and Y in the given table are respectively:

Amongst the following statements regarding adsorption, those that are valid are:
(a) $$\Delta H$$ becomes less negative as adsorption proceeds.
(b) On a given adsorbent, ammonia is adsorbed more than nitrogen gas.
(c) On adsorption, the residual force acting along the surface of the adsorbent increases
(d) With increase in temperature, the equilibrium concentration of adsorbate increases.

Simplified absorption spectra of three complexes ((i) and (ii) and (iii)) of $$M^{+n}$$ ion are provided below; their $$\lambda_{max}$$ values are marked as A, B and C respectively. The correct match between the complexes and their $$\lambda_{max}$$ values is:

(i) $$[M(NCS)_6]^{(-6+n)}$$
(ii) $$[MF_6]^{(-6+n)}$$
(iii) $$[M(NH_3)_6]^{n+}$$

Consider the reaction sequence given below:


Which of the following statements is true:

Two compounds A and B with same molecular formula $$(C_3H_6O)$$ undergo Grignard reaction with methylmagnesium bromide to give products C and D. Products C and D show following chemical tests:

TestCD
Ceric ammonium nitrate TestPositivePositive
Lucas TestTurbidity obtained after five minutesTurbidity obtained Immediately
Iodoform TestPositiveNegative


C and D respectively are:

The correct observation in the following reaction is:
$$Sucrose \xrightarrow[Cleavage \; (Hydrolysis)]{Glycosidic \; bond \; } A + B \xrightarrow[ Reagent]{Seliwanoff } ?$$

The work function of sodium metal is $$4.41 \times 10^{-19}$$ J. If photons of wavelength 300 nm are incident on the metal, the kinetics energy of the ejected electrons will be $$(h = 6.63 \times 10^{-34}$$ J s; $$c = 3 \times 10^8$$ m s$$^{-1})$$ ___________ $$\times 10^{-21}$$ J.

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