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NTA JEE Main 17th March 2021 Shift 2 - Chemistry

For the following questions answer them individually

During which of the following processes, does entropy decrease?
(A) Freezing of water to ice at 0°C
(B) Freezing of water to ice at -10°C
(C) N$$_2$$(g) + 3H$$_2$$(g) $$\to$$ 2NH$$_3$$(g)
(D) Adsorption of CO(g) and lead surface
(E) Dissolution of NaCl in water

The functional groups that are responsible for the ion-exchange property of cation and anion exchange resins, respectively, are:

Given below are two statements:
Statement-I: 2-methylbutane on oxidation with KMnO$$_4$$ gives 2-methylbutan-2-ol.
Statement-II: n-alkanes can be easily oxidised to corresponding alcohol with KMnO$$_4$$.
Choose the correct option:

Choose the correct statement regarding the formation of carbocations A and B given:

Which of the following statement(s) is (are) incorrect reason for eutrophication?
(A) excess usage of fertilisers
(B) excess usage of detergents
(C) dense plant population in water bodies
(D) lack of nutrients in water bodies that prevent plant growth
Choose the most appropriate answer from the options given below:

Match List-I and List-II:
List-I                                                       List-II
a. Haematite                                           i. Al$$_2$$O$$_3$$ . xH$$_2$$O
b. Bauxite                                               ii. Fe$$_2$$O$$_3$$
c. Magnetite                                           iii. CuCO$$_3$$ . Cu(OH)$$_2$$
d. Malachite                                            iv. Fe$$_3$$O$$_4$$
Choose the correct answer from the options given below:

Match List-I with List-II:
List-I                                                             List-II
a. [Co(NH$$_3$$)$$_6$$][Cr(CN)$$_6$$]               i. Linkage isomerism
b. [Co(NH$$_3$$)$$_3$$(NO$$_2$$)$$_3$$]              ii. Solvate isomerism
c. [Cr(H$$_2$$O)$$_6$$]Cl$$_3$$                           iii. Co-ordination isomerism
d. $$cis$$-[CrCl$$_2$$(ox)$$_2$$]$$^{3-}$$              iv. Optical isomerism
Choose the correct answer from the options given below:

Match List-I with List-II:
List-I (Chemical Compound)                                 List-II (Used as)
a. Sucralose                                                     i. Synthetic detergent
b. Glyceryl ester of stearic acid                       ii. Artificial sweetener
c. Sodium benzoate                                        iii. Antiseptic
d. Bithional                                                    iv. Food preservative
Choose the correct match:

KBr is doped with $$10^{-5}$$ mole percent of SrBr$$_2$$. The number of cationic vacancies in 1 g of KBr crystal is $$10^{14}$$ ________. (Round off to the Nearest Integer). [Atomic Mass: K: 39.1u, Br: 79.9u, $$N_A = 6.023 \times 10^{23}$$]

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A 1 molal $$K_4Fe(CN)_6$$ solution has a degree of dissociation of 0.4. Its boiling point is equal to that of another solution which contains 18.1 weight percent of a non electrolytic solute A. The molar mass of A is ________ u. (Round off to the Nearest Integer). [Density of water = 1.0 g cm$$^{-3}$$]

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A KCl solution of conductivity 0.14 S m$$^{-1}$$ shows a resistance of 4.19$$\Omega$$ in a conductivity cell. If the same cell is filled with an HCl solution, the resistance drops to 1.03$$\Omega$$. The conductivity of the HCl solution is ________ $$\times 10^{-2}$$ S m$$^{-1}$$. (Round off to the Nearest Integer).

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On complete reaction of FeCl$$_3$$ with oxalic acid in aqueous solution containing KOH, resulted in the formation of product A. The secondary valency of Fe in the product A is ________. (Round off to the Nearest Integer).

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