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NTA JEE Main 16th March 2021 Shift 2 - Chemistry

For the following questions answer them individually

The characteristics of elements X, Y and Z with atomic numbers, respectively, 33, 53 and 83 are:

Statement I: Sodium hydride can be used as an oxidising agent.
Statement II: The lone pair of electrons on nitrogen in pyridine makes it basic.
Choose the CORRECT answer from the options given below:

The correct statements about $$H_2O_2$$ are:
(A) used in the treatment of effluents.
(B) used as both oxidising and reducing agents.
(C) the two hydroxyl groups lie in the same plane.
(D) miscible with water.
Choose the correct answer from the options given below:

The INCORRECT statement regarding the structure of $$C_{60}$$ is:

The INCORRECT statements below regarding colloidal solutions is:

$$FeX_2$$ and $$FeY_3$$ are known when $$x$$ and $$y$$ are:

Arrange the following metal complex/compounds in the increasing order of spin only magnetic moment. Presume all the three, high spin system.
(Atomic numbers Ce = 58, Gd = 64 and Eu = 63.)
(a) $$(NH_4)_2[Ce(NO_3)_6]$$
(b) $$Gd(NO_3)_3$$
(c) $$Eu(NO_3)_3$$

Ammonolysis of Alkyl halides followed by the treatment with NaOH solution can be used to prepare primary, secondary and tertiary amines. The purpose of NaOH in the reaction is.

At 25°C, 50 g of iron reacts with HCl to form $$FeCl_2$$. The evolved hydrogen gas expands against a constant pressure of 1 bar. The work done by the gas during this expansion is ________ J. (Round off to the Nearest Integer)
[Given: $$R = 8.314$$ J mol$$^{-1}$$ K$$^{-1}$$. Assume, hydrogen is an ideal gas]
[Atomic mass of Fe is 55.85 u]

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In Duma's method of estimation of nitrogen, 0.1840 g of an organic compound gave 30 mL of nitrogen collected at 287 K and 758 mm of Hg pressure. The percentage composition of nitrogen in the compound is ________. (Round off to the Nearest Integer).
[Given: Aqueous tension at 287 K = 14 mm of Hg]

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A and B decompose via first order kinetics with half-lives 54.0 min and 18.0 min respectively. Starting from an equimolar non-reactive mixture of A and B, the time taken for the concentration of A to become 16 times that of B is ________ min. (Round off to the Nearest Integer).

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$$[Ti(H_2O)_6]^{3+}$$ absorbs light of wavelength 498 nm during a d-d transition. The octahedral splitting energy for the above complex is ________ $$\times 10^{-19}$$ J. (Round off to the Nearest Integer).
$$h = 6.626 \times 10^{-34}$$ Js; $$c = 3 \times 10^8$$ ms$$^{-1}$$.

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