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NTA JEE Main 10th April 2023 Shift 2 - Chemistry

For the following questions answer them individually

Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R.
Assertion A: 3.1500 g of hydrated oxalic acid dissolved in water to make 250.0 mL solution will result in 0.1 M oxalic acid solution.
Reason R: Molar mass of hydrated oxalic acid is 126 g mol$$^{-1}$$.
In the light of the above statements, choose the correct answer from the options given below:

Match List-I with List-II

List-IList-II
A16 g of CH$$_4$$(g)IWeighs 28g
B1 g of H$$_2$$(g)II$$60.2 \times 10^{23}$$ electrons
C1 mole of N$$_2$$(g)IIIWeighs 32g
D0.5 mol of SO$$_2$$(g)IVOccupies 11.4 L volume at STP

Choose the correct answer from the options given below:

Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R.
Assertion A: The energy required to form Mg$$^{2+}$$ from Mg is much higher than that required to produce Mg$$^+$$
Reason R: Mg$$^{2+}$$ is small ion and carry more charge than Mg$$^+$$
In the light of the above statements, choose the correct answer from the options given below.

Gibbs energy vs T plot for the formation of oxides is given below. For the given diagram, the correct statement is-

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Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R.
Assertion A: Physical properties of isotopes of hydrogen are different.
Reason R: Mass difference between isotopes of hydrogen is very large.
In the light of the above statements, choose the correct answer from the options given below:

In Carius tube, an organic compound 'X' is treated with sodium peroxide to form a mineral acid 'Y'. The solution of BaCl$$_2$$ is added to 'Y' to form a precipitate 'Z'. 'Z' is used for the quantitative estimation of an extra element. 'X' could be

The correct relationships between unit cell edge length 'a' and radius of sphere 'r' for face-centred and body-centred cubic structures respectively are:

Ferric chloride is applied to stop bleeding because

Match List-I with List-II.

List-I ComplexList-II Crystal Field splitting energy ($$\Delta_o$$)
A.$$[Ti(H_2O)_6]^{2+}$$I.-1.2
B.$$[V(H_2O)_6]^{2+}$$II.-0.6
C.$$[Mn(H_2O)_6]^{3+}$$III.0
D.$$[Fe(H_2O)_6]^{3+}$$IV.-0.8


Choose the correct answer from the options given below:

The correct order of the number of unpaired electrons in the given complexes is
(A) $$[Fe(CN)_6]^{3-}$$
(B) $$FeF_6^{3-}$$
(C) $$CoF_6^{3-}$$
(D) $$[Cr(oxalate)_3]^{3-}$$
(E) $$Ni(CO)_4$$
Choose the correct answer from the options given below:

The electron in the n$$^{th}$$ orbit of Li$$^{2+}$$ is excited to (n+1) orbit using the radiation of energy $$1.47 \times 10^{-17}$$ J (as shown in the diagram). The value of n is _______ Given: $$R_H = 2.18 \times 10^{-18}$$ J

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$$A(g) \rightleftharpoons 2B(g) + C(g)$$
For the given reaction, if the initial pressure is 450 mmHg and the pressure at time t is 720 mmHg at a constant temperature T and constant volume V. The fraction of A(g) decomposed under these conditions is $$x \times 10^{-1}$$. The value of x is (nearest integer) _______

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The number of endothermic process/es from the following is _______.
A. $$I_2(g) \to 2I(g)$$
B. $$HCl(g) \to H(g) + Cl(g)$$
C. $$H_2O(l) \to H_2O(g)$$
D. $$C(s) + O_2(g) \to CO_2(g)$$
E. Dissolution of ammonium chloride in water

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An aqueous solution of volume 300 cm$$^3$$ contains 0.63 g of protein. The osmotic pressure of the solution at 300 K is 1.29 mbar. The molar mass of the protein is _______ g mol$$^{-1}$$.
Given: R = 0.083 L bar K$$^{-1}$$ mol$$^{-1}$$

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The specific conductance of 0.0025M acetic acid is $$5 \times 10^{-5}$$ S cm$$^{-1}$$ at a certain temperature. The dissociation constant of acetic acid is _______ $$\times 10^{-7}$$. (Nearest integer)
Consider limiting molar conductivity of CH$$_3$$COOH as 400 S cm$$^2$$ mol$$^{-1}$$

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The number of incorrect statement/s from the following is _______
A. The successive half lives of zero order reactions decreases with time.
B. A substance appearing as reactant in the chemical equation may not affect the rate of reaction
C. Order and molecularity of a chemical reaction can be a fractional number
D. The rate constant units of zero and second order reaction are mol L$$^{-1}$$ s$$^{-1}$$ and mol$$^{-1}$$ L s$$^{-1}$$ respectively

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