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NTA JEE Main 10th April 2023 Shift 1 - Chemistry

For the following questions answer them individually

The number of molecules and moles in 2.8375 litres of O$$_2$$ at STP are respectively

The enthalpy change for the adsorption process and micelle formation respectively are

Given
(A) $$2CO(g) + O_2(g) \to 2CO_2(g)$$, $$\Delta H_1^0 = -x$$ kJ mol$$^{-1}$$
(B) $$C_{graphite} + O_2(g) \to CO_2(g)$$, $$\Delta H_2^0 = -y$$ kJ mol$$^{-1}$$
The $$\Delta H^0$$ for the reaction $$C_{graphite} + \frac{1}{2}O_2(g) \to CO(g)$$ is

Given below are two reactions, involved in the commercial production of dihydrogen H$$_2$$. The two reactions are carried out at temperature "T$$_1$$" and "T$$_2$$", respectively
$$C(s) + H_2O(g) \xrightarrow{T_1} CO(g) + H_2(g)$$
$$CO(g) + H_2O(g) \xrightarrow{T_2, Catalyst} CO_2(g) + H_2(g)$$
The temperatures T$$_1$$ and T$$_2$$ are correctly related as

Lime reacts exothermally with water to give 'A' which has low solubility in water. Aqueous solution of 'A' is often used for the test of CO$$_2$$, a test in which insoluble B is formed. If B is further reacted with CO$$_2$$ then soluble compound is formed. 'A' is

Using column chromatography, mixture of two compounds 'A' and 'B' was separated. 'A' eluted first, this indicates 'B' has

Match List I with List II

List I IndustryList II Waste Generated
(A)Steel plants(I)Gypsum
(B)Thermal power plants(II)Fly ash
(C)Fertilizer Industries(III)Slag
(D)Paper mills(IV)Bio-degradable wastes

Choose the correct answer from the options below:

Given below are two statements:
Statement I: Aqueous solution of K$$_2$$Cr$$_2$$O$$_7$$ is preferred as a primary standard in volumetric analysis over Na$$_2$$Cr$$_2$$O$$_7$$ aqueous solution.
Statement II: K$$_2$$Cr$$_2$$O$$_7$$ has a higher solubility in water than Na$$_2$$Cr$$_2$$O$$_7$$. In the light of the above statements, choose the correct answer from the options given below:

Which of the following statements are correct?
(A) The M$$^{3+}$$/M$$^{2+}$$ reduction potential for iron is greater than manganese.
(B) The higher oxidation states of first row d-block elements get stabilized by oxide ion
(C) Aqueous solution of Cr$$^{2+}$$ can liberate hydrogen from dilute acid
(D) Magnetic moment of V$$^{2+}$$ is observed between 4.4-5.2 BM
Choose the correct answer from the options given below:

Identify the correct order of reactivity for the following pairs towards the respective mechanism

(A)

image

(B)

image

(C) Electrophilic substitution

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(D) Nucleophilic substitution

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Choose the correct answer from the options given below:

Isomeric amines with molecular formula C$$_8$$H$$_{11}$$N give the following tests
Isomer P $$\Rightarrow$$ Can be prepared by Gabriel phthalimide synthesis
Isomer Q $$\Rightarrow$$ Reacts with Hinsberg's reagent to give solid insoluble in NaOH
Isomer R $$\Rightarrow$$ Reacts with HONO followed by $$\beta$$-naphthol in NaOH to give red dye.
Isomers P, Q and R respectively are

Match List-I with List-II.

List-I PolymerList-II Type/Class
A.Nylon-2-Nylon-6I.Thermosetting polymer
B.Buna-NII.Biodegradable polymer
C.Ureaformaldehyde resinIII.Synthetic rubber
D.DacronIV.Polyester

Choose the correct answer from the options given below:

The number of incorrect statement/s about the black body from the following is _______.
(A) Emit or absorb energy in the form of electromagnetic radiation.
(B) Frequency distribution of the emitted radiation depends on temperature.
(C) At a given temperature, intensity vs frequency curve passes through a maximum value.
(D) The maximum of the intensity vs frequency curve is at a higher frequency at higher temperature compared to that at lower temperature.

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The number of correct statement/s involving equilibria in physical processes from the following is _______.
(A) Equilibrium is possible only in a closed system at a given temperature.
(B) Both the opposing processes occur at the same rate.
(C) When equilibrium is attained at a given temperature, the value of all its parameters became equal
(D) For dissolution of solids in liquids, the solubility is constant at a given temperature.

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If the degree of dissociation of aqueous solution of weak monobasic acid is determined to be 0.3, then the observed freezing point will be _______ % higher than the expected/theoretical freezing point. (Nearest integer).

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A molecule undergoes two independent first order reactions whose respective half lives are 12 min and 3 min. If both the reactions are occurring then the time taken for the 50% consumption of the reactant is _______ min. (Nearest integer)

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