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NTA JEE Main 8th April 2023 Shift 2 - Chemistry

For the following questions answer them individually

Arrange the following gases in increasing order of van der Waals constant 'a'
(A) Ar
(B) CH$$_4$$
(C) H$$_2$$O
(D) C$$_6$$H$$_6$$
Choose the correct option from the following.

The incorrect statements from the following is:
A. The electrical work that a reaction can perform at constant pressure and temperature is equal to the reaction Gibbs energy.
B. $$E^\circ_{cell}$$ is dependent on the pressure.
C. $$\frac{dE_{cell}}{dT} = \frac{\Delta_r S}{nF}$$
D. A cell is operating reversibly if the cell potential is exactly balanced by an opposing source of potential difference.

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Given below are two statements:
Statement-I: Methyl orange is a weak acid.
Statement-II: The benzenoid form of methyl orange is more intense/deeply coloured than the quinonoid form.
In the light of the above statement, choose the most appropriate answer from the options given below:

Given below are two statements:
Statement I: In redox titration, the indicators used are sensitive to change in pH of the solution.
Statement II: In acid-base titration, the indicators used are sensitive to change in oxidation potential.
In the light of the above statements, choose the most appropriate answer from the options given below

Given below are two statements: One is labelled as Assertion A and the other is labelled as Reason R.
Assertion A: Sodium is about 30 times as abundant as potassium in the oceans.
Reason R: Potassium is bigger in size than sodium.
In the light of the above statements, choose the correct answer from the options given below

The descending order of acidity for the following carboxylic acid is-
(A) CH$$_3$$COOH
(B) F$$_3$$C-COOH
(C) ClCH$$_2$$-COOH
(D) FCH$$_2$$-COOH
(E) BrCH$$_2$$-COOH
Choose the correct answer from the options given below:

The statement/s which are true about antagonists from the following is/are:
A. They bind to the receptor site.
B. Get transferred inside the cell for their action.
C. Inhibit the natural communication of the body.
D. Mimic the natural messenger.
Choose the correct option from the options given below:

Match List-I with List-II

LIST-I
Coordination Complex
LIST-II
Number of unpaired electrons
A.$$[Cr(CN)_6]^{3-}$$I.0
B.$$[Fe(H_2O)_6]^{2+}$$II.3
C.$$[Co(NH_3)_6]^{3+}$$III.2
D.$$[Ni(NH_3)_6]^{2+}$$IV.4

Choose the correct answer from the options given below:

A compound 'X' when treated with phthalic anhydride in presence of concentrated H$$_2$$SO$$_4$$ yields 'Y'. 'Y' is used as an acid/base indicator. 'X' and 'Y' are respectively

For complete combustion of ethene,
$$C_2H_4(g) + 3O_2(g) \to 2CO_2(g) + 2H_2O(l)$$
the amount of heat produced as measured in bomb calorimeter is 1406 kJ mol$$^{-1}$$ at 300 K. The minimum value of T$$\Delta$$S needed to reach equilibrium is ($$-$$) kJ. (Nearest integer)
Given: R = 8.3 J K$$^{-1}$$ mol$$^{-1}$$

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The solubility product of BaSO$$_4$$ is $$1 \times 10^{-10}$$ at 298 K. The solubility of BaSO$$_4$$ in 0.1 M K$$_2$$SO$$_4$$(aq) solution is _______ $$\times 10^{-9}$$ g L$$^{-1}$$ (nearest integer).
Given: Molar mass of BaSO$$_4$$ is 233 g mol$$^{-1}$$

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If the boiling points of two solvents X and Y (having same molecular weights) are in the ratio 2:1 and their enthalpy of vaporizations are in the ratio 1:2, then the boiling point elevation constant of X is m times the boiling point elevation constant of Y. The value of m is (nearest integer).

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Coagulating value of the electrolytes AlCl$$_3$$ and NaCl for As$$_2$$S$$_3$$ are 0.09 and 50.04 respectively. The coagulating power of AlCl$$_3$$ is x times the coagulating power of NaCl. The value of x is _____.

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Match List I with List II

List I
Natural amino acid
List II
One Letter Code
(A)Glutamic acid(I)Q
(B)Glutamine(II)W
(C)Tyrosine(III)E
(D)Tryptophan(IV)Y


Choose the correct answer from the options given below: